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Oxygen in Ge : Sn

Khirunenko L.I.¹, Pomozov Yu.V.¹, Sosnin M.G.¹, Duvanskii A.V.¹, Abrosimov N.V.^2,3, Riemann H.³

¹Institute of Physics, National Academy of Sciences of Ukraine, Kiev, Ukraine
²Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Russia

Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Russia

³Institute of Crystal Growth, Berlin, Germany

Поступила в редакцию: 4 марта 2010 г.

Выставление онлайн: 19 сентября 2010 г.

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The effect of doping with tin on the nu₃ vibrational mode of oxygen in Ge has been studied. The appearance of three new series of absorption lines besides the nu₃ oxygen vibration spectra was found. The spectrum structure in each series of lines found is similar to the nu₃ oxygen spectrum structure in Ge. But unlike the nu₃ mode, the fine structure due to rotational-vibrational interaction of the nu₃ and nu₂ modes is not observed and the spectrum structure remains up to temperatures of 130 K. The found three sets of absorption lines are ascribed to the nu₃ vibration of interstitial oxygen disturbed by tin atoms located in the nearest environment. The assumption has been made that no rotation of oxygen around a Ge-Ge bond for a Ge-O-Ge quasi-molecule disturbed by a neighbour Sn atom occurs.

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