An algorithm for selective determination of components of C3H8-H2 and H2-CH4 gas mixtures in the study of temperature dependence of electrical conductivity of a semiconductor sensor based on SnO2
Kazakov S. A. 1, Dugin A. A. 1, Gagiev T. S. 1, Grevtsev M. A. 1, Sokolov A. V. 2, Arefieva O. A.3, Shishkin A. Y. 3, Khvorov V. N. 3
1Ioffe Institute, St. Petersburg, Russia
2Limited Liability Company «NIIIT», Moscow, Russia
3Scientific and Production Association PRIBOR, Saint-Petersburg, Russia
Email: kazakov59@mail.ioffe.ru

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This paper proposes an algorithm for processing measurement data of the temperature dependence of electrical conductivity of a SnO2-based gas sensor in order to determine the concentrations of individual components in C3H8-H2 and H2-CH4 mixtures. For this purpose, the sensor was calibrated for hydrogen, methane, and propane using metrologically reliable gas mixtures in dry air; the obtained concentration dependences were used to determine the coefficients of cross-sensitivity of the sensor to a particular component of the gas mixture. Using the well-known independent component method, linear equations were compiled for the studied two-component gas mixtures, the solutions of which satisfactorily describe the sensor signals obtained in the experiments. Keywords: electrical conductivity, adsorption, gas sensor, semiconductor, selectivity.
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