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Influence of the ionic subsystem on the thermoelectric effect in colloidal solutions
Sidorov A. V.
1, Grabov V. M.
2, Zaitsev. A.A.
1, Kuznetsov D.V.1
1Bunin State University, Elets, Russia
2Herzen State Pedagogical University of Russia, St. Petersburg, Russia
2Herzen State Pedagogical University of Russia, St. Petersburg, Russia
Email: dirnusir@mail.ru, zaitsev@elsu.ru
The thermoelectric effect is investigated in mixtures of colloidal solutions with ionic electrolytes in the initial state, when the formation of concentration gradients under the influence of an inhomogeneous temperature field can be neglected. Based on experimental measurements in mixtures with different concentrations of colloidal particles and ions, the conditions under with the coefficient of thermoelectric EMF is determined by the ion subsystem and under which the main contribution to the value of the thermoelectric force is made by colloidal particles are determined. Keywords: colloidal solution, thermoelectric effect, ionic subsystem.
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