Manifestation of Quantum Size Effect in Polycrystalline Graphene under Ultrahigh Pressures
Prokhorov D. A.
1,2, Zuev S. M.
1,21State Research Center of the Russian Federation Central Research Automobile and Automotive Engines Institute, Moscow, Russia
2MIREA - Russian Technological University, Moscow, Russia
Email: prohorovdmitrii97@yandex.ru, serge_zuev@mail.ru
The manifestation of the quantum size effect (QSE) was investigated in polycrystalline powdered graphene produced by mechanically exfoliating graphite in water followed by drying (Gf) under various pressing pressures (up to 0.4 GPa). The QSE was characterized by a discontinuous increase in physical properties (thermal and temperature conductivity), measured using the laser flash analysis (LFA) method and differential scanning calorimetry (DSC). Non-contact surface topography measurements of Gf were performed using optical profilometry (OP). Keywords: Quantum size effect, two-dimensional allotropic modification of carbon, polycrystalline graphene, ultra-high pressures.
- V.N. Lutskii, V.B. Sandomirskii, Yu.F. Ogrin, I.M. Lifshits, A.M. Kosevich, Yavlenie ostsillyatsii termodinamicheskikh i kineticheskikh svoistv plenok tverdykh tel, State Register of Scientific Discoveries in the USSR, No. 182, priority date: May 21, 1953 (theoretical justification) and December 10, 1965 (experimental verification) (in Russian)
- J. Xiong, S. Chen, Y. Choi, K. Matsugi, Sci. Rep., 11, 17183 (2021). DOI: 10.1038/s41598-021-96691-z
- V.V. Prut, Chislennyi raschet perekhoda grafita v almaz v metallicheskom Z-pinche (Kurchatovskii Inst., M., 2007), p. 1 (in Russian)
- Sh.M. Ismailov, S.M. Orakova, Z.A. Isaev, Kh.Sh. Yakh'yaeva, High Temp., 59 (1), 46 (2021). DOI: 10.1134/S0018151X21010053
- I.M. Abdulagatov, B.A. Grigor'ev, Z.Z. Abdulagatova, S.N. Kallaev, A.G. Bakmaev, Z.M. Omarov, Vesti Gazov. Nauki, No. 1 (46), 129 (2021) (in Russian).
- Difraktometry: rentgenovskie modeli DRON-8N i DRON-8T, Pattern Approval Certificate of Measuring Instruments No. 82575-21 (Vseross. Nauchno-Issled. Inst. Metrol., 2023) (in Russian)
- J. Fayos, J. Solid State Chem., 148 (2), 278 (1999). DOI: 10.1006/JSSC.1999.8448
- R. Siburian, H. Sihotang, S. Lumban Raja, M. Supeno, C. Simanjuntak, Orient. J. Chem., 34 (1), 182 (2018). DOI: 10.13005/ojc/340120
- T.F. Emiru, D.W. Ayele, Egypt. J. Basic Appl. Sci., 4 (1), 74 (2017). DOI: 10.1016/j.ejbas.2016.11.002
- A. Ahmad, S. Ullah, A. Khan, W. Ahmad, A.U. Khan, U.A. Khan, A.U. Rahman, Q. Yuan, Appl. Nanosci., 10 (4), 1243 (2020). DOI: 10.1007/s13204-019-01204-0
- Light-Flash-Apparatur LFA 467 HyperFlash-Serie: Methode, Technik, Applikationen zu Temperatur- und Warmeleitfahigkeit, Netzsch, 0823. https://analyzing-testing.netzsch.com/_Resources/Persistent/6/f/4/1/ 6f41f20a04ff124384a8963ed7bf4184c25e1c40/LFA_467 _HyperFlash_de_web.pdf
- DSC 204 F1 Phoenix, Technical Specifications, Netzsch, 0222. https://analyzing-testing.netzsch.com/_Resources/Persistent/ b/8/6/c/b86c2a6637064b1361d580c2bc05367072b194d6/Key _Technical_Data_en_DSC_204_F1_Phoenix.pdf
Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.
Дата начала обработки статистических данных - 27 января 2016 г.