Single tellurium whisker for the NO2 gas sensor: synthesis and rapid demonstration of sensitivity
Rabadanov M.R.
1, Krivetskiy V.V.
2, Ismailov A.M.
1, Umakhanov M. A.
1, Rabadanov M.Kh.
11Dagestan State University, Makhachkala, Dagestan Republic, Russia
2Lomonosov Moscow State University, Moscow, Russia
Email: rm777r@yandex.ru, vkrivetsky@inorg.chem.msu.ru, egdada@mail.ru, umagomed.1999.3@gmail.com, rab_mur@mail.ru
We report a method for synthesizing tellurium (Te) whiskers, both solid and hollow, with reproducible morphology and geometry. The approach based on tellurium evaporation in a hydrogen atmosphere enables precise control over whisker characteristics through the adjustment of key process parameters: crucible temperature, substrate temperature, their temperature gradient, and hydrogen pressure. The paper demonstrates the possibility of direct integration of an individual Te whisker into a micro-sensor structure and presents the results of rapid evaluation of room-temperature NO2 sensing for whiskers of two diameters (28 and 60 μm). At the concentration of 5 ppm, the sensor achieves sensitivity S~10 %, while the minimum detected concentration is 0.3 ppm for the 28 μm whisker. The device exhibits a reproducible and reversible response highlighting its potential for application in miniature low-power gas analyzers. Keywords: tellurium whiskers, gas sensors, nitrogen dioxide (NO2), sensor response.
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