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Defect structure, optical and photorefractive properties of LiNbO3 : B : Gd single crystals
Russian version
Biryukova I. V. 1, Titov R. A. 1, Efremov I. N. 1, Efremov V. V. 1,2, Bobreva L. A. 1, Teplyakova N. A. 1, Palatnikova O. V.1, Sidorov N. V. 1, Palatnikov M. N. 1
1Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences», Apatity, Murmansk region, Russia
2Institute of North Industrial Ecology Problems – Subdivision of the Federal Research Center «Kola Science Center of the Russian Academy of Sciences», Apatity, Murmansk region, Russia
Email: i.biriukova@ksc.ru, r.titov@ksc.ru, i.efremov@ksc.ru, v.efremov@ksc.ru, l.bobreva@ksc.ru, n.tepliakova@ksc.ru, o.palatnikova@ksc.ru, n.sidorov@ksc.ru, m.palatnikov@ksc.ru
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Technological approaches to obtaining nonlinear optical single-crystals of double doping LiNbO3 : B : Gd have been investigated. It is shown that simultaneous doping with boron and gadolinium allows for targeted impact on the defect structure and practical properties of lithium niobate crystals. The solid-phase synthesis-granulation method helped to obtain the initial monophase charge of lithium niobate with a concentration of B2O3 of 0.03 mol.% and Gd2O3 of 0.62 mol.% corresponding to the composition of congruent melting. It has been found that the concentration of boron in the melt after growing LiNbO3 : B : Gd crystals decreases by 3 times compared to its concentration in the initial charge. Two single crystals LiNbO_3:(0.58· 10-3 B2O3) : (0.51 mol.% Gd2O3) and LiNbO_3:(0.32· 10-3 B2O3) : (0.53 mol.% Gd2O3) were grown from a melt by the Czochralski method. Single crystals are similar in composition, and they are characterized by a low photorefractive effect, high compositional and optical uniformity. Both LiNbO3 : B : Gd crystals are characterized by high Curie temperatures (1210 oC and 1213 oC). Using the method of IR absorption spectroscopy in the region of stretching vibrations of OH groups, it was shown that the increase in the concentration of hydroxyl groups in LiNbO3 : B : Gd crystals is due to physicochemical and technological factors. Using laser conoscopy, it has been shown that the LiNbO_3:(0.32· 10-3 B2O3) : (0.53 mol.% Gd2O3) crystal has higher optical uniformity compared to the LiNbO_3:(0.58· 10-3 B2O3) : (0.51 mol.% Gd2O3) crystal. Keywords: Lithium niobate, gadolinium, boron, double doping, laser conoscopy, photoinduced light scattering, IR absorption spectroscopy, optical microscopy.
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