Pore space parameters and characteristics of SiC ceramic materials
Kapustin R. D.1, Kirillov A. O.1, Loryan V. E.1
1Merzhanov Institute of Structural Macrokinetics and Materials Science Problems, Russian Academy of Sciences, Chernogolovka, Russia
Email: kapustin-roman@mail.ru

PDF
The work is devoted to the low-temperature synthesis of porous ceramic materials based on finely dispersed SiC with sintering silicon oxide and magnesia binders. Particular attention is paid to the influence of the shape and morphology of the particles of the initial powder components on the structural parameters and characteristics of porous ceramic materials. Silicon carbide-based membranes sintered at maximum temperatures from 1000 oC to 1300 oC had average pore sizes from 0.5 to 1 μm, open porosity up to 50 %, flexural strength up to 48.5 MPa and high water permeability up to 7890 l· m-2· h-1·bar-1. The established filtration efficiency was ~ 99 % while maintaining stable permeability and physical and mechanical characteristics after multiple filtration-regeneration cycles. The obtained new knowledge about the influence of the morphology of the initial powders on the parameters of the pore space and the physical and mechanical characteristics of the synthesized porous ceramics expands the possibilities of correct prediction and provision of specified parameters of the structure and properties of materials. The results of this work can be used for the production of porous SiC membranes with high energy efficiency and technological simplicity, highly effective for micro- and ultrafiltration processes, and also having the potential for use as substrates for catalysts. Keywords: porous ceramics, pore size, porosity, permeability.
  1. V.I. Uvarov, R.D. Kapustin, A.O. Kirillov, A.S. Fedotov, M.V. Tsodikov. Refract. Ind. Ceram., 61, 355 (2020). DOI: 10.1007/s11148-020-00486-0
  2. A.O. Kirillov, R.D. Kapustin, V.I. Uvarov, O.D. Boyarchenko. Int. J. Self-Propag. High-Temp. Synth., 33 (4), 280 (2024). DOI: 10.3103/S1061386224700262
  3. V. Petri cek, M. Duvcek, L. Palatinus. Zeitschrift Fur Krist., 229 (5), 345 (2014). DOI: 10.1515/zkri-2014-1737
  4. N.T. Andrianov, V.L. Balkevich, A.V. Belyakov. Praktikum po himicheskoj tekhnologii keramiki: uchebnoe posobie dlya vuzov (OOO RIF "Strojmaterialy", M., 2005)
  5. Z.Y. Luo, W. Han, X.J. Yu, W.Q. Ao, K.Q. Liu. Ceram. Int., 45, 9007 (2019). DOI: 10.1016/j.ceramint.2019.01.234
  6. R.D. Kapustin, V.I. Uvarov, A.O. Kirillov. Open Ceram., 16, 100499 (2023). DOI: 10.1016/j.oceram.2023.100499
  7. J. Rodri guez-Viejo, F. Sibieude, M.T. Clavaguera-Mora, C. Monty. Appl. Phys. Lett., 63 (14), 1906 (1993). DOI: 10.1063/1.110644
  8. Y. Cheng, Y. Yu, C. Peng, J. Wu. Ceram. Int., 46 (8), 11297 (2020). DOI: 10.1016/j.ceramint.2020.01.158
  9. H. Qi, Y. Fan, W. Xing, L. Winnubst. J. Eur. Ceram. Soc., 30 (6), 1317 (2010). DOI: 10.1016/j.jeurceramsoc.2009.12.011
  10. D. Das, N. Kayal, G.A. Marsola, L.A. Damasceno, M.D. de M. Innocentini. Int. J. Appl. Ceram. Technol., 17, 893 (2020). DOI: 10.1111/ijac.13463
  11. C.Y. Bai, X.Y. Deng, J.B. Li, Y.N. Jing, W.K. Jiang, Z.M. Liu, Y. Li. Ceram. Int., 40 (4), 6225 (2014). DOI: 10.1016/j.ceramint.2013.11.078
  12. D. Das, K. Nijhuma, A.M. Gabriel, G.P.F. Daniel, D. de M.I. Murilo. J. Eur. Ceram., Soc., 40, 2163 (2020). DOI: 10.1016/j.jeurceramsoc.2020.01.034
  13. D. Das, N. Kayal, M.D. de M. Innocentini. Trans. Indian Ceram. Soc., 80 (3), 186 (2021). DOI: 10.1080/0371750X.2021.1934122
  14. S.Z.A. Bukhari, J.H. Ha, J. Lee, I.H. Song. Ceram. Int., 43 (10), 7736 (2017). DOI: 10.1016/j.ceramint.2017.03.079
  15. D. Liang, J. Huang, Y. Zhang, Z. Zhang, H. Chen, H. Zhang. J. Eur. Ceram. Soc., 41 (11), 5696 (2021). DOI: 10.1016/j.jeurceramsoc.2021.04.055

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245
E-mail: post@mail.ioffe.ru