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Effect of accelerated high-energy electrons with low absorbed doses on the structure of polyimide press material
Russian version
Pavlenko V.I. 1, Cherkashina N. I. 1, Noskov A. V. 2, Edamenko O. D. 1, Pavlenko Z. V. 1, Serebryakov S. V. 1
1Belgorod State Technology University named after V.G. Shukhov, Belgorod, Russia
2Moscow Technical University of Communications and Informatics (MTUCI), Moscow, Russia
Email: Serebr43@yandex.ru
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The influence of high energy accelerated electrons (E=5 MeV) and low absorbed doses (D=5-50 kGy) on structural and X-ray dislocation parameters of amorphous-crystalline polyimide press-material PI-PR-20 has been investigated by XRD method. Destruction of polyimide macromolecules at absorbed doses of 5-25 kGy is accompanied by destruction and additional amorphization of macromolecules (domains). At D=50 kGy, polymerization and crystallization of macromolecules occur with the formation of crystallites with denser packing, increased size of the coherent scattering area and minimal microdistortion of the crystalline lattice of crystallites. Keywords: polyimide, X-ray phase analysis, X-ray structural analysis, amorphous halo, polymer domains and crystallites, coherent scattering region (CSR), dislocation parameters, microdistortions.
  1. S.V. Kryuchkova, M.Yu. Yablokova, A.Yu. Alentiev, L.G. Gasanova, A.V. Kepman. Vestnik MGU, ser. 2, Khimiya, 58 (3), 126 (2017). (in Russian)
  2. H. Ohya, V.V. Kudryavtaev, S.I. Semenova. Polyimide Membranes: Applications, Fabrications, and Properties (CRC Press, London, 1997), p. 314. https://doi.org/10.1201/9780203742969
  3. M.I. Bessonov, M.M. Koton, V.V. Kudryavtseva, L.A. Laius, Poliimidy --- klass termostoikikh polimerov (Nauka, M., 1983), s. 328. (in Russian)
  4. U.S. Andropova, O.A. Serenko, E.S. Afanas'ev, D.A. Sapozhnikov, V.N. Chernik, L.S. Novikov. Poverkhnost, rentgenovskie, sinkhrotronnye i neitronnye issledovaniya, 8, 3 (2022). (in Russian) DOI: 10.31857/S1028096022080027
  5. V.M. Svetlichnyi, V.V. Kudryavtsev. Vysokomolek. soed. seriya B, (in Russian) 45 (6), 984 (2003)
  6. T.H. Hou, J.M. Bai, T.L. St. Clair. Polyimides: Materials, Chemistry and Characterization, ed. by C. Feger, M.M. Khojasteh, J.E. McGrath (Elsevier, Amsterdam, 1989), p. 169
  7. O.A. Anan'eva, V.K. Milinchuk, D.L. Zagorskii. Khimiya vysokikh energiy, 41 (4), 271 (2007). (in Russian)
  8. V.K. Milinchuk, E.R. Klinshpont, I.P. Shelukhov. Izvestiya vuzov, ser. yadernaya energetika, 2, 108 (2002). (in Russian)
  9. O.F. Pasevich. Issledovanie svoistv i struktury poliimidnykh plenok posle vozdeistviya faktorov kosmicheskogo prostranstva nizkikh zemnykh orbit (Kand. diss. NIFKhI im. L.Ya. Karpova, M., 2006), 22 s. (in Russian)
  10. D.J. Liaw, K.L. Wang, Y.C. Huang, K.R. Lee, J.Y. Lai. C.S. Ha. Prog. Pol. Sci., 37, 907 (2012). https://doi.org/10.1016/j.progpolymsci.2012.02.005
  11. I. Gouzman, E. Grossman, R. Verker, N. Atar, A. Bolker, N. Eliaz. Appl. Adv. Mater., 31 (18), 1807738 (2019). https: //doi.org/10.1002/adma.201807738
  12. V.K. Milinchuk, V.I. Tupikov. Radiatsionnaya stoikost' organicheskikh materialov (Energoatomizdat, M., 1986), 271 s. (in Russian)
  13. V.N. Kuleznev, Chimiya i fizika polimerov (Khimiya, M., 1988), 312 s. (in Russian)
  14. Yu.V. Shutilin. Fiziko --- khimiya polimerov (PoliMir, Voronezh, 2012), 838 s. (in Russian)
  15. N.I. Cherkashina, V.I. Pavlenko, V.M. Abrosimov, V.I. Trofimov, S.V. Budnik, R.S. Churyukin, V.M. Gavrish. Acta Astronautica, 184, 59 (2021). DOI: 10.1016/j.actaastro.2021.03.032
  16. E.N. Kablov, O.V. Startsev, I.G. Deev, E.F. Nikishin. Vse materialy. Entsiklopedicheskii spravochnik, 10, 40 (2012). (in Russian)
  17. A.I. Akishin. Razvitie kosmicheskogo materialovedeniya v NIIYaF MGU. 50 let NII yadernoi fiziki (MGU, M., 1997), 87-234. (in Russian)
  18. M. Kotera. J. Appl. Phys., 52, 997 (1981)
  19. A.I. Akishin, V.B. Baikal'tsev, Yu.I. Tyutrin. Vozdeistvie elektronnykh potokov na zashchitnye pokrytiya solnechnykh batarei (Atomizdat, M.,1991), 69 s. (in Russian)
  20. V.I. Pavlenko, N.I. Cherkashina, A.V. Noskov. Poverkhnost'. Rentgenovskie, sinkhrotronnye i neytronnye issledovaniya, 2, 54 (2021). (in Russian) DOI: 10.31857/S1028096020110126
  21. A.K. Pikaev. Sovremennaya radiatsionnaya chimiya. Tverdoe telo i polimery. Prikladnye aspekty (Nauka, M., 1987), 448 s. (in Russian)
  22. S.V. Tsybulya, D.A. Yatsenko. Zhurnal strukturnoi chimii, 53, 155 (2012). (in Russian)
  23. A.K. Shtol'ts, A.I. Medvedev, L.V. Kurbatov. Rentgenovskii analiz mikronapryazhenii i razmera oblastei kogerentnogo rasstoyaniya v polikristallicheskikh materialakh (UGTU-UPI, Ekaterinburg, 2005), s. 2-23. (in Russian)
  24. F.R. Studenikin. Modifikatsiya puchka uskorennykh elektronov dlya povysheniya ravnomernosti radiatsionnoi obrabotki obluchaemykh obektov (Kand. diss., MGU., M., 2022), s. 41-45. (in Russian)
  25. Z. Joi. Polimer J., 22, 909 (1990)
  26. V.I. Poddubnyi, V.K. Lavrent'ev. O forme amorfnogo galo na difraktogramme amorfno-kristallicheskikh polimerov (Institut vysokomolekulyarnykh soedinenii, M., 1989), p. 354-356. (in Russian)
  27. S.S. Dong, W.Z. Shao, L. Vang, H.J. Ve, L. Zhen. RSC Adv., 8, 28152 (2018). DOI: 10.1039/C8RA05744C
  28. L.A. Oksent'evich, M.M. Badaeva, G.I. Tuleninova, A.N. Pravednikov. Vysokomolek. soed., 19 (3), 553 (1977). (in Russian)
  29. P.H. Hermans, J.W. Street. Makromolek. Chem., 74 (1), 133 (1964)
  30. N.L. Mathakari, V.N. Bhozaskar, D.D. Sanjay. Mater. Sci. Eng.: B. 168 (1-3), 122 (2010). https://doi.org/10.1016/j.mseb.2009.11.005
  31. F. Uoker. Khimicheskie i fizicheskite svoistva ugleroda (Mir, M., 1969), p. 366. [Per. s angl.: P.L. Walker. Chemistry \& Physics of Carbon (Marcel Dekker, NY., 1969), v. 4.]
  32. E.A. Plis, D.P. Engelhart, R. Cooper, W.R. Johnston, D. Ferguson, R. Hoffmann. Adv. Polyimide Films: Preparation, Properties and Applications, 9 (10), 1999 (2019). https://doi.org/10.3390/app9101999
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