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Brominated porous carbon material for terahertz radiation shielding
Russian version
Baskakova K. I. 1, Sedelnikova O. V.1, Nishchakova A. D.1, Shlyakhova E. V.1, Fedorenko A. D.1, Paddubskaya A. G.2, Valynets N. I.2, Bulusheva L. G.1, Fedoseeva Y. V. 1, Okotrub A. V.1
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Institute for Nuclear Problems, Belarusian State University, Minsk, Belarus
Email: baskakova@niic.nsc.ru, o.sedelnikova@gmail.com, nishchakova@niic.nsc.ru, shlyakhova@niic.nsc.ru, fedorenko@niic.nsc.ru, paddubskaya@gmail.com, nadezhda.volynets@gmail.com, bul@niic.nsc.ru, fedoseeva@niic.nsc.ru, spectrum@niic.nsc.ru
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Porous carbon material obtained by thermal decomposition of acetonitrile on template CaO particles was brominated in saturated bromine vapor at room temperature. This modification led to the addition of 3 at% bromine and increased its electrical conductivity by 3.2 times. Polymer films were made from polystyrene with the addition of starting or brominated porous carbon materials at different concentrations (from 1 to 10 wt%) to study the effect of bromination on the electromagnetic properties of composite materials in the frequency range from 0.1 to 1.3 THz. An increase in the shielding of terahertz radiation with increasing filler concentration has been shown. At low contents, the shielding efficiency of the composites filled with brominated porous carbon material increased by several times compared with the samples filled with the initial one that was associated with the modification of the electronic structure of porous carbon material during the bromination procedure. Keywords: porous carbon material, bromination, polymer composite, shielding of terahertz electromagnetic radiation.
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