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Effect of nanodiamonds with different surface states on ion channel packing and proton conductivity of composite perfluorosulfone membranes
Russian version
Lebedev V.T. 1, Kulvelis Yu. V. 1, Primachenko O. N. 2, A. S. Odinokov3, Marinenko E. A. 2, Shvidchenko A. V. 4, A.I. Kuklin5, O.I. Ivankov5
1Konstantinov Petersburg Nuclear Physics Institute, National Research Center Kurchatov Institute, Gatchina, Russia
2Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia
3Russian Scientific Center "Applied Chemistry", St. Petersburg, Russia
4Ioffe Institute, St. Petersburg, Russia
5Frank Neutron Physics Laboratory, Joint Nuclear Research Institute, Dubna, Moscow oblast, Russia
Email: lebedev_vt@pnpi.nrcki.ru, kulvelis_yv@pnpi.nrcki.ru, alex-prima@mail.ru, emarinenkospb@gmail.com, avshvid@mail.ioffe.ru
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A copolymer of the AquivionoledR type was modified with detonation diamonds (size 4-5 nm, concentration 0.25-5.0 wt.%) and studied using neutron scattering, measuring the packing period of ion channels in the matrix. Positively charged diamonds with a hydrogen-saturated surface at a concentration of 0.5 wt.% provided a 30 % increase in the ionic conductivity of the membranes at a temperature of 50 oC due to compaction of the packing of channel assemblies. Due to the electrostatic attraction of the components, a more developed conductive diamond-copolymer interface was created in such membranes than in composites with negatively charged ionic groups of the components. When the matrix was filled with hydrophobic fluorinated diamonds (1 wt.%), a fivefold decrease in ionic conductivity was observed due to the disruption of the connectivity of ion channels. The found correlations between the structure and ionic conductivity of the composites depending on the type and amount of filler are important for the targeted formation of membranes upon modification with nanoparticles. Keywords: membranes, diamonds, conductivity, structure.
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