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The influence of absorption current on the results of measuring the ionic conductivity of the LiPON solid electrolyte
Russian version
Rudy A. S.1, Novozhilova A. V.2
1Demidov State University, Yaroslavl, Russia
2Russian Peoples’ Friendship University, Moscow, Russia
Email: rudy@uniyar.ac.ru, alena.novozhilova.2014@mail.ru
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An alternative interpretation of the impedance spectra of the LiPON solid electrolyte is proposed. It is suggested that the experimental value of conductivity is due to the absorption and displacement current, while the drift current is mainly shielded by the electrical double layer. The impedance of an alternative LiPON equivalent circuit containing a non-ideal absorption element is calculated. It is shown that the Bode diagrams of the alternative equivalent circuit well approximate the experimental curves, and the conductivity values are consistent with theoretical data and calculations based on the concentration and mobility of lithium ions. Keywords: LiPON, impedance spectroscopy, electrical double layer, absorption element, displacement current.
  1. J.B. Bates, N.J. Dudney, G.R. Gruzalski, R.A. Zuhr, A. Choudhury, C.F. Luck, J.D. Robertson, Solid State Ion., 53-56, 647 (1992). DOI: 10.1016/0167-2738(92)90442-R
  2. J. Bates, N. Dudney, G. Gruzalski, R. Zuhr, A. Choudhury, C. Luck, J. Robertson, J. Power Sources, 43, 103 (1993). DOI: 10.1016/0378-7753(93)80106-Y
  3. J.B. Bates, G.R. Gruzalski, N.J. Dudney, C.F. Luck, X. Yu, Solid State Ion., 70-71, 619 (1994). DOI: 10.1016/0167-2738(94)90383-2
  4. J.B. Bates, N.J. Dudney, D.C. Lubben, G.R. Gruzalski, B.S. Kwak, X. Yu, R.A. Zuhr, J. Power Sources, 54, 58 (1995). DOI: 10.1016/0378-7753(94)02040-A
  5. X. Yu, J.B. Bates, G.E. Jellison, Jr., F.X. Hart, J. Electrochem. Soc., 144, 524 (1997). DOI: 10.1149/1.1837443
  6. X. Yu, J.B. Bates, G.E. Jellison, Jr., in Proc. of the Symp. on thin film solid ionic devices and materials (Electrochemical Society, Inc., 1995), vol. 95-22, p. 23
  7. J.B. Bates, N.J. Dudney, C.F. Luck, B.C. Sales, R.A. Zuhr, J.D. Robertson, J. Am. Ceram. Soc., 76, 929 (1993). DOI: 10.1111/j.1151-2916.1993.tb05317.x
  8. Y. Hamon, A. Douard, F. Sabary, C. Marcel, P. Vinatier, B. Pecquenard, A. Levasseur, Solid State Ion., 177, 257 (2006). DOI: 10.1016/j.ssi.2005.10.021
  9. L. Li, S. Liu, X. Xue, H. Zhou, Ionics, 24, 351 (2018). DOI: 10.1007/s11581-017-2209-4
  10. N. Mascaraque, J.L.G. Fierro, A. Duran, F. Munoz, Solid State Ion., 233, 73 (2013). DOI: 10.1016/j.ssi.2012.12.017
  11. C.S. Nimisha, G.M. Rao, N. Munichandraiah, G. Natarajan, D.C. Cameron, Solid State Ion., 185, 47 (2011). DOI: 10.1016/j.ssi.2011.01.001
  12. L. Le Van-Jodin, F. Ducroquet, F. Sabary, I. Chevalier, Solid State Ion., 253, 151 (2013). DOI: 10.1016/j.ssi.2013.09.031
  13. F. Munoz, A. Duran, L. Pascual, L. Montagne, B. Revel, A.C.M. Rodrigues, Solid State Ion., 179, 574 (2008). DOI: 10.1016/j.ssi.2008.04.004
  14. B. Fleutot, B. Pecquenard, H. Martinez, A. Levasseur, Solid State Ion., 206, 72 (2012). DOI: 10.1016/j.ssi.2011.11.009
  15. Y. Su, J. Falgenhauer, A. Polity, T. Leichtweib, A. Kronenberger, J. Obel, S. Zhou, D. Schlettwein, J. Janek, B.K. Meyer, Solid State Ion., 282, 63 (2015). DOI: 10.1016/j.ssi.2015.09.022
  16. A. Lopez-Grande, G.C. Mather, F. Munoz, J. Mater. Chem. A, 11, 12282 (2023). DOI: 10.1039/D3TA00724C
  17. A.S. Rudy, M.V. Lebedev, A.V. Novozhilova, Phys. Solid State, 65, 1465 (2023)
  18. A.S. Rudyi, M.E. Lebedev, A.A. Mironenko, L.A. Mazaletskii, V.V. Naumov, A.V. Novozhilova, I.S. Fedorov, A.B. Churilov, Russ. Microelectron., 49, 345 (2020). DOI: 10.1134/S1063739720040095
  19. K.S. Cole, R.H. Cole, J. Chem. Phys., 9, 341 (1941). DOI: 10.1063/1.1750906
  20. A. Rudy, A. Mironenko, V. Naumov, A. Novozhilova, A. Skundin, I. Fedorov, Batteries, 7 (2), 21 (2021). DOI: 10.3390/batteries7020021
  21. S.V. Vasilev, M.E. Lebedev, L.A. Mazaletskii, A.V. Metlitskaya, A.A. Mironenko, V.V. Naumov, A.V. Novozhilova, A.S. Rudyi, I.S. Fedorov, Russ. Microelectron., 46, 424 (2017). DOI: 10.1134/S1063739717060099

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