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The mechanism of copper (II) oxide particles dispersion in a solution of polymethyl methacrylate
Russian version
Danilaev M. P. 1, Drobushev S.V. 1, Karandashov S. A. 1, Kuklin V. A. 1, Lipatnikov K. A. 1, Lounev I. V. , Faizullin K.V. 1
1Tupolev Kazan National Research Technical University (KAI), Kazan, Tatarstan, Russia
Email: danilaev@mail.ru, iamkvova@yandex.ru
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An effective method for producing dispersion-filled polymer composite materials with a low agglomerate content is based on in situ - technology-the formation of filler particles directly in the polymer matrix during composite synthesis. Of particular interest is the synthesis of dispersed particles from precursors within minireactors, where synthesis conditions differ from ambient conditions. The interaction of such minireactors with the environment can initiate the dispersion of particles synthesized in situ. A method is proposed for forming films of dispersion-filled polymer composites from a polymethyl methacrylate solution in toluene with the in situ generation of copper(II) oxide particles within minireactors. It is shown that the formation of minireactors in the polymer solution is due to the development of a polymer shell around the charge of the precursor (copper hydroxide) during its thermal decomposition. It was shown that heating these minireactors in a microwave field leads to the formation of water vapor within them, an increase in pressure, and rupture of the shell, thereby dispersing copper (II) oxide particles. The highest dispersion efficiency is achieved in a saturated solution of polymethyl methacrylate in toluene. The results of a study of polymer films obtained from solutions with varying concentrations of dispersed particles are presented. Keywords: polymer solution, minireactors, in situ method, dispersed particles, polymer composite material.
  1. A.P. Sheinerman, S.A. Krasnitskii. Pis'ma v ZhTF, (in Russian). 47, 37 (2021). DOI: 10.21883/PJTF.2021.17.51385.18844
  2. G.E. Rani, R. Murugeswari, S. Siengchin, N. Rajini, M.A. Kumar. J. Mater. Res. Technol., 19, 1836 (2022). DOI: 10.1016/j.jmrt.2022.05.147
  3. A.K. Mazitova, I.I. Zaripov, G.K. Aminova, M.V. Ovod, N.L. Suntsova. Nanotechnologies in Construction, 14, 294 (2022)
  4. E.C. Demir, A. Benkaddour, D.R. Aldrich, M.T. McDermott, C.I. Kim, C. Ayranci. J. Composite Mater., 56, 1591 (2022). DOI: 10.1177/00219983221076639
  5. S. Samal. Powder Technol., 366, 43 (2020). DOI: 10.1016/j.powtec.2020.02.054
  6. S. Siraj, A.H. Al-Marzouqi, M.Z. Iqbal, W. Ahmed. Polymers, 14, 4830 (2022). DOI: 10.3390/polym14224830
  7. J. Zhu, C. Abeykoon, N. Karim. Intern. J. Lightweight Mater. Manufacture, 4, 370 (2021). DOI: 10.1016/j.ijlmm.2021.04.003
  8. V. Kuklin, S. Karandashov, E. Bobina, S. Drobyshev, A. Smirnova, O. Morozov, M. Danilaev. Intern. J. Molecular Sci., 24, 1 (2023). DOI: 10.3390/ijms24032515
  9. A.R. Singh, P.S. Dhumal, M.A. Bhakare, K.D. Lokhande, M.P. Bondarde, S. Some. Separation and Purification Technol., 286, 1 (2022). DOI: 10.1016/j.seppur.2021.120380
  10. E. Bobina, M. Danilaev, S.M.R.H. Hussein, S. Karandashov, V. Kuklin, I. Lounev, K. Faizullin. Karbala Intern. J. Modern Sci., 10, 277 (2024). DOI: 10.33640/2405-609X.3 357
  11. A. Kamal, M. Ashmawy, A.M. Algazzar, A.H. Elsheikh. Proceed. Institution Mechan. Engineers, Part C: J. Mechan. Engineering Sci., 236, 4843 (2022). DOI: 10.1177/09544062211055662
  12. S. Sain, M. Bose, D. Ray, A. Mukhopadhyay, S. Sengupta, T. Kar, C.J. Ennis, P.K. Rahman, M. Misra. J. Reinforced Plastics Composites, 32, 147 (2013). DOI: 10.1177/0731684412449699
  13. Yu.D. Tret'yakov, A.V. Lukashin, A.A. Eliseev. Uspekhi khimii, (in Russian). 73, 974 (2004). DOI: 10.1070/RC2004v073n09ABEH000918
  14. J.H. Swisher, L. Jibril, S.H. Petrosko, C.A. Mirkin. Nature Rev. Mater., 7, 428 (2022). DOI: 10.1038/s41578-021-00402-z
  15. M.P. Danilaev, N.V. Dorogov, S.V. Drobushev, S.A. Karandashov, M.A. Klabukov, V.A. Kuklin. Condens. Matter Interphases, 25, 27 (2023). DOI: 10.17308/kcmf.2023.25/10943
  16. H.F. Huber, C. Thies. J. Polym. Sci. A-2 Polym. Phys., 8, 71 (1970). DOI: 10.1002/pol.1970.160080106
  17. S. Coppola, L. Miccio, Z. Wang, G. Nasti, V. Ferraro, P. Luca Maffettone, V. Vespini, R. Castaldo, G. Gentile, P. Ferraro. RSC Advances, 12, 31215 (2022). DOI: 10.1039/D2RA04300A
  18. H.S. Nalwa. Handbook of low and high dielectric constant materials and their applications, two-volume set (Academic Press, United States, 1999)
  19. D.W. Scott, G.B. Guthrie, J.F. Messerly, S.S. Todd, W.T. Berg, I.A. Hossenlopp, J.P. McCullough. J. Phys. Chem., 66, 911 (1962). DOI: 10.1021/j100811a038
  20. J.C. Salamone. Polymeric materials encyclopedia, Twelve volume set (CRC press, United States, 2020)
  21. B.M. Faroldi, J.M. Conesa, A. Guerrero-Ruiz, I. Rodri guez-Ramos. Appl. Catalysis A: General, 629, 118419 (2022). DOI: 10.1016/j.apcata.2021.118419
  22. I.M. Uzunov, D.G. Klissurski. Thermochim. Acta, 81, 353 (1984). DOI: 10.1016/0040-6031(84)85142-4
  23. O.G. Morozov. Sensors, 21, 8225 (2021). DOI: 10.3390/s21248225
  24. A.N. Alhussein, M.R. Qaid, T. Agliullin, B. Valeev, O. Morozov, A. Sakhabutdinov. Sensors, 25, 2289 (2025). DOI: 10.3390/s25072289
  25. M.P. Danilaev, S.A. Karandashov, V.A. Kyklin, A.Zh. Sakhabutdinov, S. Khussein. Nauchnoe priborostroenie, 31 (2), 35 (2021) (in Russian). DOI: 10.18358/np-31-2-i3543
  26. A.Z. Sakhabutdinov, S.M.R.H. Hussein, A.R. Ibragimova, V. Kuklin, M.P. Danilaev, L.Y. Zaharova. Karbala Intern. J. Modern Sci., 7 (3), 7 (2021). DOI: 10.33640/2405-609X.3122
  27. M.P. Danilaev, S.V. Drobyshev, M.A. Klabukov, V.A. Kuklin, D.A. Mironova. Nanotechnol. Russia, 16, 162 (2021). DOI: 10.1134/S263516762102004X
  28. H. Liu, S. Wang, R. Zhuo, Y. Duan, J. Wang, Y. Li, J. Yang. Powder Technol., 444, 119803 (2024). DOI: 10.1016/j.powtec.2024.119803
  29. A.V. Blinov, A.A. Gvozdenko, A.N. Golik, A.A. Blinova, K.S. Slyadneva, M.A. Pirogov, D.G. Maglakelidze. Vesnit Moskovskogo gos. tekh. un-ta im. N.E. Baumana. Ser. Estestvennye nauki, 103 (4), 95 (2022) (in Russian). DOI: 10.18698/1812-3368-2022-4-95-109
  30. H. Bresch, V.-D. Hodoroaba, A. Schmidt, K. Rasmussen, H. Rauscher. Nanomaterials, 12, 2238 (2022). DOI: 10.3390/nano12132238
  31. Y.M. Poon, F.G. Shin. J. Mater. Sci., 39, 1277 (2004). DOI: 10.1023/B:JMSC.0000013886.21054.e4
  32. V. Navarkhele, A. Navarkhele. Intern. J. Thermodynamics, 25 (3), 1 (2022). DOI: 10.5541/ijot.1017174
  33. A. Schonhals, F. Kremer. Analysis of Dielectric Spectra Broadband Dielectric Spectroscopy (Springer, Berlin, Heidelberg, 2003), p. 59-98. DOI: 10.1007/978-3-642-56120-7_3
  34. A. Van Roggen. IEEE Transactions on Electrical Insulation, 25 (1), 95 (2002). DOI: 10.1109/14.45236
  35. Y. Li, X. Yin, Y. Si, J. Yu, B. Ding. Chem. Eng. J., 398, 125626 (2020). DOI: 10.1016/j.cej.2020.125626
  36. S. Chen, D. Wu, C. Xu, M. Ma, Y. Shi, K. Yuan, R. Xu, X. Wang. Polymers Adv. Tech., 32, 1230 (2021). DOI: 10.1002/pat.5172
  37. D. Blond, V. Barron, M. Ruether, K.P. Ryan, V. Nicolosi, W.J. Blau, J.N. Coleman. Adv. Funct. Mater., 16, 1608 (2006). DOI: 10.1002/adfm.200500855
  38. R. Pervin, P. Ghosh, M.G. Basavaraj. RSC Adv., 9, 15593 (2019). DOI: 10.1039/C9RA01331H
  39. A. Mujtaba, M. Keller, S. Ilisch, H.-J. Radusch, T. Thurn-Albrecht, K. Saalwachter, M. Beiner. Macromolecules, 45, 6504 (2012). DOI: 10.1021/ma300925p

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