Highly reflective silver mirror under annealing and hydrothermal exposure
Tereschenko I. B.1,2, Marchiy G. V.1, Samsonov D.S.1,2, Mukhin E.E.1,2, Kapustin Yu.V.3, Kalganov V.D.4, Gubal A.R.1, Komarevtsev I.M.1,5
1Ioffe Institute, St. Petersburg, Russia
2Spectral-Tech, St. Petersburg, Russia
3National Research Center “Kurchatov Institute”, Moscow, Russia
4Interdisciplinary Resource Centre for Nanotechnology SPbU, St.-Petersburg, Russia
5Peter the Great Saint-Petersburg Polytechnic University, St. Petersburg, Russia
Email: i.tereschenko@mail.ioffe.ru, georgiy.marchiy@mail.ioffe.ru, d.samsonov@mail.ioffe.ru, e.mukhin@mail.ioffe.ru, vanec@bk.ru

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The highly reflective Ag-based thin-film coating for the ITER optical diagnostic mirror was tested under annealing at 250-310 oC and steam exposure. The Ag grain growth triggered by elevated temperature was identified as the main reason for the deterioration of the coating reflectivity and structure. The SiNx/(SiOx/SiN_x)2 nanolaminate barrier composition over the Ag layer was found to effectively suppress the corrosive effect of steam. Keywords: surface degradation, silver mirrors, annealing, corrosion.
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