Anodic aluminum oxide formed in aqueous solutions of chelated complex zinc and cobalt compounds
Poznyak A. A.
1, Knörnschild G. H.
2, Pligovka A. N.
1, Larin T.D.
11Belarusian State University of Informatics and Radioelectronics, Minsk, Belarus
2Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, Brasil
Email: poznyak@bsuir.by, gerhard.hans@ufrgs.br, pligovka@bsuir.by, tilar2001@tut.by
The galvanostatic anodizing results of specially prepared high-purity aluminum in aqueous solutions of complex compounds K3[Co(C2O_4)_3] and K2[Zn(edta)] of various concentrations in the current density ranges 1.5-1.10·102 and 1.5-30 mA·cm-2, respectively. The kinetic features of anodizing have been established, indicating the occurrence of an oscillatory electrochemical process. Morphological features of a flaky and loose nature for K2[Zn(edta)] and monolithic for K3[Co(C2O_4)_3], uncharacteristic for anodic aluminum oxide, were revealed. The elemental composition, IR spectroscopic and photoluminescent characteristics of the formed oxides are shown. Keywords: anodic aluminum oxide, chelated complex compounds, anodizing.
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