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Effect of the introduction of single-walled carbon nanotubes and reduced graphene oxide on the structure formation and specific resistance of yhydrogels during photopolymerization
Russian version
Savelyev M. S. 1,2
1Institute of Biomedical Systems, National Research University of Electronic Technology, MIET, Moscow, Zelenograd, Russia
2Institute for Bionic Technologies and Engineering, Sechenov First Moscow State Medical University, Sechenov University, Moscow, Russia
Email: savelyev@bms.zone
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The effect of ultrasonic treatment of aqueous dispersions of single-walled carbon nanotubes (SWCNTs) and reduced graphene oxide (RGO) on the structure formation and specific resistivity of photopolymerized biopolymer hydrogels (matrix: collagen/BSA/chitosan/eosin Y) has been studied. For this purpose, dynamic light scattering was used in combination with specific resistivity measurements. The optimal ratio of 1 to 1 for SWCNTs with a hydrodynamic radius of 0.49 μm (80 min treatment) and RGO with 0.21 μm (80 min treatment) provided a specific resistivity of 14 Ω·cm, while hydrogels retain the ability to swell up to 200 %. The analysis of the dependence of temperature and normalized optical transmission on the duration of laser photopolymerization made it possible to determine the optimal temperature of the liquid biopolymer precursor 28 oC, which ensures maximum reproducibility of the specific resistivity of hydrogels produced by photolithography Keywords: Hydrogel, negative photoresist, temperature, dynamic light scattering, nonlinear absorption cross section, carbon nanotubes, reduced graphene oxide, biocompatibility, neurointerface.
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