Three-stage synthesis of composite nanomaterials based on iron and gold by laser ablation and assisted ultrasound
The paper presents the results of a three-stage synthesis of composite nanoparticles based on a combination of femtosecond laser ablation and ultrasound exposure. The synthesis was carried out by laser ablation in deionized water and by laser ablation in a gaseous medium (argon or air) in the presence of a magnetic or electrostatic field. The approach used leads to the formation of composite magneto-plasmon nanoparticles with a "core-satellite" configuration. For the two types of composite nanoparticles under consideration, a redshift of the plasmon resonance position is observed from 520 nm (initial gold nanoparticles) to 545-548 nm (composite magneto-plasmon nanoparticles). The heating of solutions of composite Fe3O4-Au and PVP α-Fe-Au with concentrations of 0.06 mg/ml and 0.07 mg/ml was 10.6 oC and 10.6 oC, respectively. The experimental data obtained confirm the possibility of using the proposed combined approach to create composite nanoparticles with magnetic and plasmonic properties. This approach allows flexible variation of synthesis conditions to obtain nanoparticles with the necessary properties. Keywords: Keywords: laser ablation, laser fragmentation, magnetic nanoparticles, gold nanoparticles, composite nanoparticles, photothermal response, magneto-plasmon nanoparticles.
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