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Effect of crystal-chemical growth conditions of single crystals of trigonal ferroborates Ho0.5Nd0.5Fe3(BO_3)4 with huntite structure on their magnetic properties
Russian version
Titova V.R. 1, Gudim I.A.1, Shabanov A.V.1, Eremin E.V.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Email: eev@iph.krasn.ru
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This work aimed to compare the magnetic properties of Ho0.5Nd0.5Fe3(BO3)4 single crystals grown from different solution melts: based on bismuth trimolybdate and lithium tungstate. Single crystals of this ferroborate from lithium-tungstate melt solution were grown for the first time. The chemical composition of ferroborates was determined using energy dispersive spectroscopy. It was found that Bi3+ ions replace Nd3+ ions (~ 5 % at.) in the case of using bismuth trimolybdate solvent. When using a lithium-tungstate melt solution, impurities from the solvent do not enter the crystal matrix. From magnetic studies, the Neel temperatures T N and paramagnetic Curie temperatures were determined, effective magnetic moments μeff calculated, and phase diagrams of the magnetic state "temperature-magnetic field" of the studied compounds were constructed. Keywords: solution-melt method, magnetic dielectrics, antiferromagnets.
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