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Effect of continuous-wave CO2 Laser beam scan rate on the composition of laser-induced graphene
Russian version
Zonov R. G. 1, Vorobyov V. L. 1, Gil'vutdinov F.Z. 1, Mogileva T. N. 1, Mikheev G. M. 1
1Udmurt Federal Research Center, Ural Branch Russian Academy of Sciences, Izhevsk, Russia
Email: znv@udman.ru, Vasily_L.84@udman.ru, gilmutdinov@udman.ru, mogileva@udman.ru, mikheev@udman.ru
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Film samples of laser-induced graphene (LIG) were synthesized on the surface of polyimide film through line-by-line scanning with a focused beam of a continuous-wave carbon dioxide laser. The structure and chemical composition of the near-surface layer of the synthesized material were investigated as a function of the scanning speed v of the laser beam. It was found that a decrease in v from 400 to 10 mm/s leads to an increase in nitrogen concentration by more than 11 times. At an optimal laser power of 0.55 W and a speed of v=10 mm/s, the nitrogen concentration reaches 5.7 at.%. It has been demonstrated that the increase in nitrogen concentration with a decrease in v occurs due to the pyridine and pyrrole configurations of nitrogen in the nanocrystalline structure of graphite, which is accompanied by a significant reduction in the sheet resistance of LIG. The obtained results correlate with the previously established multiple increase in the electrochemical capacitance of LIG with a decrease in v. Keywords: polyimide film, laser pyrolysis, X-ray photoelectron spectroscopy, elemental composition, nitrogen doping.
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