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Hydrogen defects in diamonds: research and definition of content of N3VH content using secondary ion mass spectrometry and infrared spectroscopy
Russian version
Shilobreeva S.N. 1, Khmelnitsky R. A. 2, Ber B. Ya. 3, Kazantsev D. Yu. 3, Dravin V. A.2, Prokofiev V. Yu.4, Tarelkin S. A. 5, Tokarev M. V. 3
1V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Moscow, Russia
2Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russia
3Ioffe Institute, St. Petersburg, Russia
4Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry Russian Academy of Sciences, Moscow, Russia
5"TECHNOLOGICAL INSTITUTE FOR SUPERHARD AND NOVEL CARBON MATERIALS OF NATIONAL RESEARCH CENTRE "KURCHATOV INSTITUTE", Troitsk, Moscow, Russia
Email: shilobre@mail.ru, khmelnitskyra@lebedev.ru, boris.ber@mail.ioffe.ru, dukazantsev@mail.ioffe.ru, tarelkinsa@yandex.ru, mvtokarev@mail.ioffe.ru
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The concentration of hydrogen and N3VH defects in natural diamonds was determined using secondary ion mass spectrometry (SIMS) and infrared (IR) spectroscopy. A method for quantitative analysis of hydrogen was proposed based on the creation of reference samples directly in the studied samples by implantation of hydrogen. A linear correlation was established between the IR absorption of the paintwork material at 3107 cm-1 and the hydrogen concentration determined by SIMS: C_H=S*N3VHI3107, where S*N3VH=(2.15± 1.44)· 1017 cm-1. A detailed characteristics of main hydrogen defects in diamonds is given. Keywords: IR spectroscopy, secondary ion mass spectrometry, diamond, hydrogen, N3VH defects.
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