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Luminescence of lanthanide(III) sulfate crystals under photo-, X-ray and triboexcitation
Russian version
Tukhbatullin A. A. 1, Panova N. A. 1, Sharipov G. L. 1
1Institute of Petrochemistry and Catalysis UFRC RAS, Ufa, Russia
Email: adiska0501@gmail.com, naduasha.panova99@mail.ru, glus@anrb.ru
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The comparative studies of the luminescent characteristics (photo-, x-ray excited, triboluminescence spectra, lifetime of excited states and quantum yield of photoluminescence) of crystalline hydrates of lanthanide(III) sulfates (Ce, Pr, Sm, Eu, Gd, Tb, Dy) were carried out. The positions of the Ln(III) ions bands in the triboluminescence spectra of the studied compounds coincide with the positions in the photo- and x-ray excited luminescence spectra, which indicates the identity of the luminescence emitters. It has been shown that the triboluminescence spectrum of inorganic lanthanide salts in the air atmosphere is caused by gas (emitter N2) and solid-state (emitter - Ln(III)) components. The excitation of Ln3+ triboluminescence occurs according to the type of electroluminescence, namely due to the separation and recombination of charge carriers in the electric field of the crystal volume. Keywords: lanthanide(III) sulfates, photoluminescence, x-ray excited luminescence, triboluminescence, quantum yield, lifetime.
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