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Crystal and electronic structure of the composite compound Bi1-xLaxFe1-yMnyO3+σ according to X-ray diffraction and X-ray electron spectroscopy
Russian version
Googlev K. A. 1, Kozakov A. T.2, Kochur A. G. 1, Nikolskii A. V. 2, Rudskaya A. G. 3
1Rostov State University for Railway Transportation, Rostov-on-Don, Russia
2Scientific Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia
3Southern Federal University, Rostov-on-Don, Russia
Email: googlev@rambler.ru
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Based on X-ray photoelectron spectroscopy data, the ratio of the proportions of trivalent and tetravalent manganese Mn3+/Mn4+ in the ceramic composite compound Bi1-xLaxFe1-yMnyO3+σ was determined. Profiles of X-ray photoelectron La3d-, La4d-, Fe2p- and Mn2p-spectra were calculated in the isolated ion approximation, taking into account multiplet splitting in the final state of photoionization. Good agreement with experiment was obtained Keywords: X-ray photoelectron spectroscopy, valence state, mu ltiplet splitting, X-ray diffraction.
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