On the mechanism of selective population of the 3p1 level of the neon atom in He-Ne plasma
Ivanov V. A. 1, SkobloYu.E 1
1St. Petersburg State University, St. Petersburg, Russia
Email: v.a.ivanov@spbu.ru

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In the spectroscopic studies of helium-neon plasma carried out earlier, a pronounced selectivity of the population of the 3p1 level (according to Paschen), the upper one from the group of levels of the 2p54p configuration of the Ne atom, was revealed. As the helium pressure increased, up to 60% of the intensity of all transitions 2p54p-> 2p53s was concentrated in the 352.05 nm line (3p1-> 1s2). In the present work, a mechanism is proposed for the growth of the relative population of the 3p1 level with increasing He pressure, associated with the features of the collisional kinetics of the 3pi states of the 2p54p configuration. The reason for the significantly faster depletion of the lower 3pi levels (i ≥ 2) compared to 3p1, apparently, is the features of the mutual arrangement of the adiabatic terms of the Ne(2p54p) + He(1s2 1S0) system. The mechanism of formation of selective population of the 3p1 level considered in this work can be realized in a mixture of helium with neon and cannot be realized in pure neon, which corresponds to the results of spectroscopic studies. Model calculations of the part of the spectrum related to transitions 3p1, 3p4, 3p2-> 1sj were carried out for a fixed distribution of population flows 3p1, 3p4, 3p2 and different helium pressures. Good agreement between the measurement results and the results of numerical modeling is observed. Keywords: helium-neon plasma, selective population, inelastic collisions of atoms, adiabatic terms, numerical modeling of excited state population.
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