Spectroscopic study of structural defects caused by oxygen vacancies in solid solutions of stabilized zirconium dioxide
Ryabochkina P. A.
1, Pankratov V.
2, Lomonova E E.
3, Sidorova N V.
1, Artemov S. A.
1, Gerasmov M.V
11Ogarev Mordovian State University, Saransk, Russia
2Institute of Solid State Physics, University of Latvia, Riga, Latvia
3Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
Email: ryabochkina@freemail.mrsu.ru, vpank@latnet.lv, lomonova@lst.gpi.ru, ya.natalka2112@yandex.ru, sergey560113@gmail.com, gerasimov.mv12@gmail.com
Using spectral-luminescent methods upon excitation by synchrotron radiation, structural defects caused by oxygen vacancies were revealed in ZrO2-Y2O3-Ho2O3, ZrO2-Y2O3-Er2O3, ZrO2-Y2O3 crystals. The positions of the energy levels of oxygen vacancies V+1 and V+2 located near the conduction band are determined. Keywords: zirconium dioxide, rare earth ion, oxygen vacancy, luminescence spectra, excitation spectra, synchrotron radiation.
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