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Evolution of the spectral and structural characteristics of borates formed during the interaction of lanthanum and scandium oxides with a potassium tetraborate melt
Russian version
DOI: 10.21883/PSS.2023.05.56052.35
Shmurak S.Z. 1, Kedrov V.V. 1, Kiselev A.P. 1, Fursova T.N. 1, Zver'kova I.I. 1
1Osipyan Institute of Solid State Physics RAS, Chernogolovka, Russia
Email: shmurak@issp.ac.ru, fursova@issp.ac.ru, kiselev@issp.ac.ru, zverkova@issp.ac.ru
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The structure, morphology, IR spectra, as well as luminescence spectra and luminescence excitation spectra of europium-doped borates formed during the interaction of lanthanum and scandium oxides with a potassium tetraborate melt at 970oC with the general formula La0.99-xScxEu0.01BO3 were studied. It is shown that with an increase in the Sc3+ concentration, three compounds are successively formed: LaBO3, LaSc3(BO3)4, and ScBO3. At 0≤ x≤ 0.26, the samples are single-phase and have the structure of LaBO3 aragonite. Within the range of 0.26<x<0.75, the samples are two-phase and contain the structures of LaBO3 aragonite and LaSc3(BO3)4 huntite. At 0.75≤ x≤0.85, LaSc3(BO3)4 is observed. Within the range of 0.85<x≤0.97, the samples are two-phase and consist of LaSc3(BO3)4 huntite and ScBO3 calcite. At 0.97<x≤0.99, the ScBO3 samples have a calcite structure. Correspondence between the structure and spectral characteristics of these compounds was established. Keywords: phosphors for LEDs, rare earth orthoborates, X-ray diffraction analysis, IR spectroscopy, luminescence spectra.
  1. E.F. Shubert, J.K. Kim. Science 308, 1274 (2005)
  2. X. Zhang, X. Fu, J. Song, M.-L. Gong. Mater. Res. Bull. 80, 177 (2016)
  3. C. Mansuy, J.M. Nedelec, C. Dujardin, R. Mahiou. Opt. Mater. 29, 6, 697 (2007)
  4. J.-P. Meyu, T. Jensen, G. Huber. IEEE J. Quantum Electron 30:913 (1994)
  5. D. Lu, Z. Pan, H. Zwang, J. Wang. Opt. Mater. Express 5, 8, 1822 (2015)
  6. A.B. Kuznetsov, K.A. Kokh, N.G. Kononova, V.S. Shevchenko, S.V. Rashchenko, D.M. Ezhov, A.Y. Jamous, A. Bolatov, B. Uralbekov, V.A. Svetlichnyi, A.E. Kokh. J. Alloys Comp. 851, 156825 (2021).
  7. V.V. Mikhailin, D.A. Spassky, V.N. Kolobanov, A.A. Meotishvili, D.G. Permenov, B.I. Zadneprovski. Rad. Measurements 45, 307 (2010)
  8. J. Yang, G. Zhang, L. Wang, Z. You, S. Huang, H. Lian, J. Lin. J. Solid State Chem. 181, 2672 (2008)
  9. G. Blasse, B.C.Grabmaier. Luminescent Materials. Springer-Verlag, Berlin--Heiderberg (1994). 233 p
  10. Jun Yang, Chunxia Li, Xiaoming Zhang, Zewei Quan, Cuimiao Zhang, Huaiyong Li, Jun Lin. Chem. Eur. J. 14, 14, 4336 (2008)
  11. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, I.M. Shmyt'ko, FTT 57, 1, 19 (2015). (in Russian)
  12. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.M. Shmyt'ko. FTT 57, 8, 1558 (2015). (in Russian)
  13. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zverkova, E.Yu. Postnova. FTT 63, 7, 933 (2021). (in Russian)
  14. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zverkova, E.Yu. Postnova. FTT 63, 10, 1615 (2021). (in Russian)
  15. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, FTT 62, 12, 2110 (2020). (in Russian)
  16. J. Holsa. Inorg. Chim. Acta 139, 1--2, 257 (1987)
  17. E.M. Levin, R.S. Roth, J.B. Martin. Am. Miner. 46, 9--10, 1030 (1961)
  18. G. Chadeyron, M. El-Ghozzi, R. Mahiou, A. Arbus, C. Cousseins. J. Solid State Chem. 128, 261 (1997)
  19. D. Santamari a-Perez, O. Gomis, J. Angel Sans, H.M. Ortiz, A. Vegas, D. Errandonea, J. Ruiz-Fuertes, D. Martinez-Garcia, B. Garcia-Domene, Andre L. J. Pereira, F. Javier Manjon, P. Rodriguez-Hernandez, A. Munoz, F. Piccinelli, M. Bettinelli, C. Popescu. J. Phys. Chem. C 118, 4354 (2014)
  20. Wen Ding, Pan Liang, Zhi-Hong Liu. Mater. Res. Bull. 94, 31 (2017)
  21. Wen Ding, Pan Liang, Zhi-Hong Liu. Solid State Sci. 67, 76 (2017)
  22. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, S.S. Khasanov, FTT 63, 12, 2142 (2021). (in Russian)
  23. N.I. Steblevskaya, M.I. Belobeletskaya, M.A. Medkov. Zhurn. neorgan. khimii 66, 4, 440 (2021). (in Russian)
  24. J. Guang, C. Zhang, C. Wang, L. Liu, C. Huang, S. Ding. Cryst. Eng. Commun. 14, 579 (2012)
  25. J. Zhang, M. Yang, H. Jin, X. Wang, X. Zhao, X. Liu, L. Peng. Mater. Res. Bull. 47, 247 (2012)
  26. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, FTT 64, 8, 955 (2022). (in Russian)
  27. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, FTT 64, 12, 2000 (2022). (in Russian)
  28. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, FTT 64, 4, 474 (2022). (in Russian)
  29. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, FTT 65, 2, 312 (2023). (in Russian)
  30. Heng-Wei Wei, Li-Ming Shao, Huan Jiao, Xi-Ping Jing. Opt. Mater. 75, 442 (2018)
  31. R. Nayar, S. Tamboli, A.K. Sahu, V. Nayar, S.J. Dhoble. J. Fluoresc. 27, 251 (2017)
  32. S.K. Omanwar, N.S. Savala Appl. Phys. A 123, 673 (2017)
  33. A. Haberer, Kaindl R, Huppertz H. Z. Naturforsch. Chem. Sci. B 65, 1206 (2010).
  34. R. Velchuri, B.V. Kumar, V.R. Devi, G. Prasad, D.J. Prakash, M. Vital. Mater. Res. Bull. 46, 8, 1219 (2011)
  35. Jin Teng-Teng, Zhang Zhi-Jun, Zhang Hui, Zhao Jing-Tai. J. Inorganic Mater. 28, 10, 1153 (2013)
  36. K.K. Palkina, V.G. Kuznetsov, L.A. Butman, B.F. Dzhurinsky, Koordinatsionnaya khimiya 2, 2, 286 (1976). (in Russian)
  37. S. Lemanceau, G. Bertrand-Chadeyron, R. Mahiou, M. El-Ghozzi, J.C. Cousseins, P. Conflant, R.N. Vannier. J. Solid State Chem. 148, 229 (1999)
  38. N. Akcamli, D. Agaogullari, O. Balci, M. Lutfi \:Ovecoglu, I. Duman. Ceram. Int. 42, 10045 (2016)
  39. C.E. Weir, E.R. Lippincott. J. RES. Natl. Bur. Std.-A. Phys. Chem. A 65, 3, 173 (1961)
  40. A. Szczeszak, T. Grzyb, St. Lis, R.J. Wiglusz. Dalton Transact. 41, 5824 (2012)
  41. Ling Li, Shihong Zhou, Siyuan Zhang. Solid State Sci. 10, 1173 (2008)
  42. D.A. Keszler, H. Sun, Acta Crystallogr. Cryst. Struct. Commun. C 44, 1505 (1988)
  43. I.M. Shmytko. FTT 61, 11, 2210 (2019). (in Russian)
  44. M. He, G. Wang, Z. Lin, W. Chen, S. Lu, Q. Wu. Mater. Res. Innovation 2, 345 (1999)
  45. G. Wang, M. He, W. Chen, Z. Lin, S. Lu, Q. Wu. Mater. Res. Innovat. 2, 6, 341 (1999)
  46. A.G. Ryabukhin, Izv. Chelyabinskogo nauch. tsentra 4, 33 (2000). (in Russian)
  47. C.E. Weir, E.R. Lippincott. J. Res. Natl. Bur. Std. 65A, 3, 173 (1961)
  48. W.C. Steele, J.C. Decius. J. Chem. Phys. 25, 6, 1184 (1956)
  49. A.D. Mills. Inorganic Chem. 1, 4, 960 (1962)
  50. I.A. Kaurova, D.M. Gorshkov, G.M. Kuz'micheva, V.B. Rybakov. Fine Chem. Technol. 13, 6, (2018)
  51. V.S. Kurazhkovskaya, E.Yu Borovikova, N.I. Leonyuk, E.V. Koporulina, E.L. Belokoneva. Zhurn.struct. khimii 49, 6, 1074 (2008). (in Russian)
  52. V.S. Kurazhkovskaya, E.A. Dobretsova, E.Yu Borovikova, V.V. Mal'tsev, N.I. Leonyuk. Zhurn.struct. khimii 52, 4, 721 (2011). (in Russian)
  53. E.Yu. Borovikova, E.A. Dobretsova, K.N. Boldyrev, V.S. Kurazhkovskaya, V.V. Maltsev, N.I. Leonyuk. Vibrational Spectroscopy 68, 82 (2013)
  54. E.A. Dobretsova, E.Yu Borovikova, K.N. Boldyrev, V.S. Kurazhkovskaya, N.I. Leonyuk. Optika i spektroskopiya 116, 1, 85 (2014). (in Russian)
  55. E.Yu. Borovikova, K.N. Boldyrev, S.M. Aksenov, E.A. Dobretsova, V.S. Kurazhkovskaya, N.I. Leonyuk, A.E. Savon, D.V. Deyneko. Opt. Mater. 49, 304 (2015)
  56. E. Belokoneva, A. Azizov, N. Leonyuk. Zhurn. strukturn. khimii 22, 3, 196 (1981). (in Russian)
  57. N.I. Leonyuk, A.V. Pashkova, T.I. Timchenko. Kristallografiya 33, 5, 1287 (1988). (in Russian)
  58. E.L. Belokoneva, T.I. Timchenko. Kristallografiya 28, 6, 1118 (1983). (in Russian)
  59. G.E. Malashevich, V.N. Sigaev, N.V. Golubev, E.Kh. Mamadzhanova, A.V. Danilchik, A.V. Zubelevich, E.V. Lutsenko. Pis'ma v ZhETF 92, 8, 547 (2010). (in Russian)
  60. S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, I.I. Zver'kova. FTT 55, 2, 336 (2013). (in Russian)
  61. M.A. Elyashevich, Spektroskopiya redkikh zemel', GITTL, M. (1953). 456 p. (in Russian).
  62. M.I. Gaiduk, V.F. Zolin, L.S. Gaigerova. Spektry lyuminestsentsii evropiya. Nauka, M. (1974), 195 p. (in Russian)
  63. A. Mayolet, W. Zhang, P. Martin, B. Chassigneux, J.C. Krupa. J. Electrochem. Soc. 143, 1, 330 (1996)
  64. S.Z. Shmurak, A.P. Kiselev, V.V. Sinitsyn, I.M. Shmyt'ko, A.S. Aronin, B.S. Red'kin, E.G. Ponyatovsky, FTT 48, 1, 48 (2006). (in Russian)
  65. S.Z. Shmurak, A.P. Kiselev, N.V. Klassen, V.V. Sinitsyn, I.M. Shmyt'ko, B.S. Red'kin, S.S. Khasanov. IEEE Trans. Nucl. Sci. 55, 1--3, 1128 (2008)
  66. S.Z. Shmurak, A.P. Kiselev, D.M. Kurmasheva, B.S. Red'kin, V.V. Sinitsyn, ZhETF 137, 5, 867 (2010). (in Russian).

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