Crystals of the phenazine coordination polymer with the third order symmetry axis: formation, properties
Kompan M.E.1, Malyshkin V.G.
1, Boiko M.E.
1, Sharkov M.D.
1, Sapurina I.Yu.
2, Shishov M.A.
2
1Ioffe Institute, St. Petersburg, Russia
2Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia
Email: Kompan@mail.ioffe.ru, mal@gromco.com, boikomix@gmail.com, mischar@mail.ru, sapurina@mail.ru, shv_misha@mail.ru
Unusual quasi-two-dimensional crystals of a regular triangular shape, self-formed in the process of obtaining a coordination polymer based on phenazine and silver, are described and studied. X-ray diffraction studies were carried out, the interplanar distance was determined, and the spectra of Raman scattering were obtained. A mechanism is proposed that can cause the appearance of triangular crystals from nuclei of hexagonal symmetry. Keywords: X-ray diffractometry, Raman scattering, phenazines - organic crystals.
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