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Impedancemetry of Ag2S nanocrystallites embedded in nanoporous glasses
Russian version
DOI: 10.21883/PSS.2022.14.54347.176
Ilinskiy A.V. 1, Castro R.A.2, Pashkevich M.E.3, Popova I.O.2, Sidorov A.I.4, Shadrin E.B.1
1Ioffe Institute, St. Petersburg, Russia
2Herzen State Pedagogical University of Russia, St. Petersburg, Russia
3Peter the Great Saint-Petersburg Polytechnic University, St. Petersburg, Russia
4ITMO University, St. Petersburg, Russia
Email: shadr.solid@mail.ioffe.ru
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The temperature dependences of the dielectric spectra of Ag2S nanocrystallites synthesized inside the channels of nanoporous glasses NPG-17 with an average diameter of filamentous pores of 17 nm are studied. The macroscopic mechanism for the occurrence of the frequency dependence of the electrical response of a nanoporous structure NPG-17 + Ag2S is proposed. Formation of the model of mechanism is based superionic phase transition in Ag2S nanocrystallites fixed inside the channels of nanoporous glass is discussed. Keywords: silver sulfide, Ag2S, nanoporous glasses, nanostructured materials, impedancemetry.
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