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Effect of yttrium content on luminescent properties and charge localization in (0.23ZrO2-0.77HfO2)-Y2O3-Eu2O3 ceramics
Russian version
Dementeva E. V. 1, Gusev G.A. 1, Dementev P. A.1, Orekhova K. N. 1, Zamoryanskaya M. V. 1
1Ioffe Institute, St. Petersburg, Russia
Email: dementeva@mail.ioffe.ru, ggusev@mail.ioffe.ru, orekhova.kseniia@gmail.com, zam@mail.ioffe.ru
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The main objective of the study was to determine the effect of yttrium concentration on charge localization in (0.23ZrO2-0.77HfO2)-Y2O3-Eu2O3 ceramics. In this work, (0.23ZrO2-0.77HfO2)-Y2O3-Eu2O3 ceramics with different yttrium contents were synthesized by the co-precipitation technique, and its composition and luminescent properties were studied. All samples were stabilized in the cubic phase and exhibited red luminescence with characteristic emission bands of Eu3+ ions. It was shown that an increase in the yttrium content leads to an increase in the content of electron traps associated with oxygen vacancies. The obtained results can be used in the development of new thermoluminescent detectors. Keywords: hafnium dioxide, zirconium dioxide, yttrium oxide, europium, cathodoluminescence, ceramics, thermoluminescent detectors, oxygen vacancies, electron traps.
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