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Structure and properties of glycine-modified iron oxide nanoparticles for biomedical applications
Russian version
Kamzin A. S.1, Kozenkov I2, sviridova T.2, Rodionova V.2, Omelyanchik A2,3
1Ioffe Institute, St. Petersburg, Russia
2Immanuel Kant Baltic Federal University, Kaliningrad, Russia
3Department of Chemistry and Industrial Chemistry (DCIC), University of Genova, Genova, Italy
Email: askam@mail.ioffe.ru
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Properties, a structure and sizes of the iron oxide particles produced by co-precipitation in the presence of glycine have been studied in a dependence on an amount of glycine in a reaction mixture from 0.0 mol, 0.1 mol, 0.3 mol and 0.6 mol. It was shown by data of Mossbauer spectroscopy that the synthesized particles are single-phase magnetite spinel ferrite nanoparticles (Fe3O4). It is shown by results of X-ray diffraction and Mossbauer studies that with an increase of the glycine concentration (0.1 mol, 0.3 mol and 0.6 mol) the particle sizes decrease from 11 nm, 10 nm and to 6 nm, respectively. The data of the Mossbauer studies of the particles indicate differences of the magnetic structures of a surface layer and a volume of the particles, which significantly affects the nanoparticle properties. An approach for creating special iron oxide nanoparticles has been developed for diagnostics and therapy (theranostics) of human diseases. Keywords: magnetic nanoparticles, functionalization, magnetic properties, magnetic structure.
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