Physics of the Solid State
Volumes and Issues
Home » Physics of the Solid State » Year 2025, issue 9 » Article p. 1609
<<<>>>
Magnetic properties of ultra-small NiFe2O4 nanoparticles system coated with PVA
Russian version
Balaev D. A.1, Krasikov A. A.1, Velikanov D. A.1,2, Stolyar S. V.1,2, Shokhrina A. O.2, Balaev A. D.1, Iskhakov R. S.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia
Email: dabalaev@iph.krasn.ru
PDF
The static magnetic properties of a system of NiFe2O4 nanoparticles (average size 4.5 nm) coated with polyvinyl alcohol (PVA) were studied. The analysis of the magnetization curves allowed us to conclude that the small particle size causes a pronounced "core/shell" structure with structural and magnetic order in the core and, accordingly, disorder in the particle shell. The thickness of the disordered surface layer is ~1 nm, and the ferrimagnetic core can only be formed in particles of about 4 nm or more in size. The coating of the particles leads to their spatial separation and a decrease in the intensity of magnetic interparticle interactions, which follows from a comparison with the data for a reference sample with identical particle sizes without PVA coating. The weakening of magnetic interparticle interactions is manifested in a decrease in the superparamagnetic blocking temperature of the magnetic moments of the particles caused by the ferrimagnetically ordered core. Another important consequence of the spatial separation of particles is the collapse of the common integrated surface for a cluster of particles, which is realized in the reference sample. This is manifested in a smaller value of the coercive force of the magnetic hysteresis loop (at T=4.2 K) of the studied system of particles coated with PVA. Also, the paper discusses the processes of freezing of atomic magnetic moments located in disordered areas of particles. Keywords: nickel ferrite, nanoparticles, magnetic interparticle interactions.
  1. H.A. Khan, M.K. Sakharkar, A. Nayak, U. Kishore, A. Khan. Nanobiomaterials 2018, 357 (2018)
  2. M. Amiri, M. Salavati-Niasari, A. Akbari. Adv. Colloid Interface Sci. 265, 29 (2019)
  3. Ali, T. Shah, R. Ullah, P. Zhou, M. Guo, M. Ovais, Z. Tan, Y. Rui. Front. Chem. 9, 629054 (2021)
  4. S. Ohkoshi, A. Namai, K. Imoto, M. Yoshikiyo, W. Torora, K. Nakagawa, M. Komine, Y. Miyamoto, T. Nasu, S. Oka, H. Tokoro. Sci. Rep. 5, 14414 (2015)
  5. A. Namai, M. Yoshikiyo, K. Yamada, S. Sakurai, T. Goto, T. Yoshida, T. Miyazaki, M. Nakajima, T. Suemoto, H. Tokoro, S. Ohkoshi. Nat. Commun. 3, 1035 (2012)
  6. X. Batlle, C. Moya, M. Escoda-Torroella, \`O. Iglesias, A.F. Rodriguez, A. Labarta. J. Magn. Magn. Mater. 543, 168594 (2022)
  7. C. Djurberg, P. Svedlindh, P. Nordblad, M. F. Hansen, F. B dker, S. M rup. Phys. Rev. Lett. 79, (N25) 5154 (1997)
  8. G.F. Goya, T.S. Berquo, F.C. Fonseca, M.P. Morales. J. Appl. Phys. 94, 3520 (2003)
  9. S. M rup, D.E. Madsen, C. Fradsen, C.R.H. Bahl, M.F. Hansen. J. Phys.: Condens. Matter 19, 213202 (2007)
  10. J.M. Vargas, W.C. Nunes, L.M. Socolovsky, M. Knobel, D. Zanchet. Phys. Rev. B 72, 184428 (2005)
  11. M. Suzuki, S.I. Fullem, I.S. Suzuki, L. Wang, Ch.-J. Zhong. Phys. Rev. B 79, 024418 (2009)
  12. S.V. Komogortsev, V.A. Fel'k, O.A. Li. J. Magn. Magn. Mater. 473, 410 (2019)
  13. W.C. Nunes, L.M. Socolovsky, J.C. Denardin, F. Cebollada, A.L. Brandl, M. Knobel. Phys. Rev. B 72, 212413 (2005)
  14. M. Knobel, W.C. Nunes, H. Winnischofer, T.C.R. Rocha, L.M. Socolovsky, C.L. Mayorga, D. Zanchet. Journal of Non-Crystalline Solids 353, 743 (2007)
  15. F. Fabris, Kun-Hua Tu, C.A. Ross, W.C. Nunes. J. Appl. Phys. 126, 173905 (2019)
  16. C.A.M. Vieira, R. Cabreira Gomes, F.G. Silva, A.L. Dias, R. Aquino, A.F.C. Campos, J. Depeyrot. J. Phys.: Condens. Matter 31, 17580 (2019)
  17. T.S. Berquo, J.J. Erbs, A. Lindquist, R.L. Penn, S.K. Banerjee. J. Phys.: Condens. Matter 21, 176005 (2009)
  18. K. Nadeem, M. Kamran, A. Javed, F. Zeb, S.S. Hussain, M. Mumtaz, H. Krenn, D.V. Szabo, U. Brossmann, X. Mu. Solid State Sciences 83, 43 (2018)
  19. A.A. Krasikov, Yu.V. Knyazev, D.A. Balaev, S.V. Stolyar, V.P. Ladygina, A.D. Balaev, and R.S. Iskhakov, JETP 137 (N. 6), 903 (2023)
  20. Yu.V. Knyazev, D.A. Balaev, S.A. Skorobogatov, D.A. Velikanov, O.A. Bayukov, S.V. Stolyar, R.N. Yaroslavtsev, R.S. Iskhakov. Phys. Rev. B 107, 115413 (2023)
  21. D.A. Balaev, A.A. Krasikov, S.V. Stolyar, R.N. Yaroslavtsev, S.A. Skorobogatov, D.A. Velikanov, R.S. Iskhakov. Physics of the Solid State 66, 11, 1829 (2024)
  22. Yu.V. Knyazev, D.A. Balaev, S.A. Skorobogatov, D.A. Velikanov, O.A. Bayukov, S.V. Stolyar, V.P. Ladygina, A.A. Krasikov, and R.S. Iskhakov. Physics of Metals and Metallography, 125, 4, 377 (2024)
  23. D.A. Balaev, A.A. Krasikov, Yu.V. Knyazev, S.V. Stolyar, A.O. Shokhrina, A.D. Balaev*, and R.S. Iskhakov. JETP Letters 120, 10, 751 (2024)
  24. D.A. Balaev, A.A. Krasikov, S.A. Skorobogatov, S.V. Stolyar, R.N. Yaroslavtsev, R.S. Iskhakov. JETP Letters 122, 1, 48 (2025)
  25. D. Caruntu, G. Caruntu, Ch.J. O'Connor. J. Phys. D: Appl. Phys. 40, 5801 (2007)
  26. D.A. Balaev, S.V. Semenov, A.A. Dubrovskiy, S.S. Yakushkin, V.L. Kirillov, O.N. Martyanov. J. Magn. Magn. Mater. 440, 199 (2017)
  27. M. Vasilakaki, F. Gemenetzi, E. Devlin, D.K. Yi, S.N. Riduan, S.S. Lee, J.Y. Ying, G.C. Papaefthymiou, K.N. Trohidou. J. Magn. Magn. Mater. 522, 167570 (2021)
  28. Yu.V. Knyazev, D.A. Balaev, S.V. Stolyar, A.O. Shokhrina, D.A. Velikanov, A.I. Pankrats, A.M. Vorotynov, A.A. Krasikov, S.A. Skorobogatov, M.N. Volochaev, O.A. Bayukov, R.S. Iskhakov. J. Magn. Magn. Mater. 613, 172675 (2025)
  29. S.V. Stolyar, O.A. Li, E.D. Nikolaeva, N.M. Boev, A.M. Vorotynov, D.A. Velikanov, R.S. Iskhakov, V.F. P.yankov, Yu.V. Knyazev, O.A. Bayukov, A.O. Shokhrina, M.S. Molokeev, A.D. Vasil'ev. Physics of the Solid State 65, 6, 963 (2023)
  30. S.V. Stolyar, O.A. Li, E.D. Nikolaeva, A.M. Vorotynov, D.A. Velikanov, Yu.V. Knyazev, O.A. Bayukov, R.S. Iskhakov, V.F. P'yankov, M.N. Volochaev. Physics of Metals and Metallography, 124, 2, 174 (2023).
  31. S.V. Stolyar, O.A. Li, A.M. Vorotynov, D.A. Velikanov, N.G. Maksimov, R.S. Iskhakov, V.P. Ladygina, A.O. Shokhrina. Bulletin of the Russian Academy of Sciences: Physics 88, 536 (2024)
  32. S.V. Stolyar, E.D. Nikolaeva, O.A. Li, D.A. Velikanov, A.M. Vorotynov, V.F. Pyankov, V.P. Ladygina, A.L. Sukhachev, D.A. Balaev, R.S. Iskhakov. Inorganic Materials: Applied Research 15, 927 (2024)
  33. S.V. Stolyar, I.G. Vazhenina , A.O. Shokhrina, E.D. Nikolaeva, O.A. Li, R.S. Iskhakov, A.V. Belyi. Physics of the Solid State 67, 7, 1273 (2025)
  34. A.D. Balaev, Y.V. Boyarshinov, M.M. Karpenko and B.P. Khrustalev. Instrum. Exp. Tech.(Engl. Transl.); (United States), 26, N3, (1985)
  35. D.A. Velikanov. Siberian Aerospace Journal 14, no. 2, 176, (2013)
  36. R.H. Kodama, A.E. Berkowitz, E.J. McNiff, S. Foner. J. Appl. Phys. 81, 5552 (1997)
  37. R.J. Tackett, A.W. Bhuiya, C.E. Botez. Nanotechnology 20, 445705 (2009)
  38. S. Mitra, K. Mandal, P. Anil Kumar. J. Magn. Magn. Mater. 306, 254 (2006)
  39. A. Millan, A. Urtizberea, N.J.O. Silva, F. Palacio, V.S. Amaral, E. Snoeck, V. Serin. J. Magn. Magn. Mater. 312, L5 (2007)
  40. A.P. Safronov, I.V. Beketov, S.V. Komogortsev, G.V. Kurlyandskaya, A.I. Medvedev, D.V. Leiman, A. Larranaga, S.M. Bhagat. AIP Adv. 3, 052135 (2013)
  41. D. Zakutna, D. Nivzvnansky, L.C. Barnsley, E. Babcock, Z. Salhi, A. Feoktystov, D. Honecker, S. Disch. Phys. Rev. X 10, 031019 (2020)
  42. Li Wang, J. Li, M. Lu, H. Dong, J. Hua, S. Xu, H. Li. J. Supercond. Nov. Magn. 28, 191 (2015)
  43. A.A. Krasikov, D.A. Balaev. JETP 136, 1, 97 (2023)
  44. Yu. Sitikhadze, Kh. Sato. Ferrity. Mir, M. (1964). 407 s. (in Russian)
  45. A. Adam, Z. Ali, E. Abdeltwab, Y. Abbas. Journal of Ovonic Research 5 (5), 157 (2009).

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245
E-mail: post@mail.ioffe.ru