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Paramagnetic centers of uncontrolled impurities in ZnWO4 doped with rare earths and lithium
Russian version
Vazhenin V.A. 1, Artyomov M.Yu.1, Potapov A.P.1, Soubbotin K.A.2,3, Fokin A.V.1, Zimina A.V.2,3, Titov A. I.2, Lis D.A.2
1Ural Federal University (Institute of Natural Sciences and Mathematics), Yekaterinburg, Russia
2Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
3Mendeleev University of Chemical Technology, Moscow, Russia
Email: vladimir.vazhenin@urfu.ru
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Single crystals of ZnWO4 grown by the Czochralski method and doped with Yb or Tm, as well as Li, were studied by the EPR method. Transitions of monoclinic centers of Fe3+, Cr3+ and Gd3+ were observed, similar to the previously studied spectra in lithium-free crystals. Spectra of triclinic centers detected in samples free of lithium admixture and attributed to dimers (paramagnetic ion - zinc vacancy) were not observed. However, new satellites appeared, accompanying the transitions of monoclinic centers in a wide range of magnetic field orientations. It is reasonable to assume that these centers (triclinic and monoclinic) arise as a result of association of paramagnetic ions with lithium ions in zinc positions. Measurement of the orientational behavior of intradoublet (in the case of Gd3+ - and interdoublet) transitions in two orthogonal planes made it possible to determine the parameters of their spin Hamiltonians. Keywords: zinc tungstate, impurity ions, iron group, REE, paramagnetic resonance.
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