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Luminescent properties investigation of ZBLAN:Er3+/Ho3+ fluoride glass under laser excitation at a wavelength of 1.94 μm
Russian version
Egolin V. A. 1, Savikin A. P. 1, Kurashkin S. V. 1, Marugin A. V. 1
1Lobachevsky State University, Nizhny Novgorod, Russia
Email: vitaly.egolin@mail.ru, savikin@rf.unn.ru, kurashkin@rf.unn.ru, marugin@rf.unn.ru
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A series of fluoride glass samples of the composition ZBLAN:1%Er3+, ZBLAN:1%Ho3+, ZBLAN:1%Er3++X%Ho3+ (X=0.25,0.5,1 mol.%) is synthesized. Based on the transmission spectra of the compounds ZBLAN:1%Ho3+ and ZBLAN:1%Er3+, the Judd-Ofelt intensity parameters for Ho3+ and Er3+ ions in synthesized samples are determined. Up-conversion luminescence of ZBLAN:Er3+/Ho3+ glass under excitation Tm3+:YAP- laser radiation with a wavelength of 1.94 μm is investigated. The up-conversion luminescence spectra of the visible range exhibit bands in the regions of 545 and 655 nm. The highest intensity was observed for the red lines at a wavelength of 655 nm, which correspond to the transitions 4F9/2->4I15/2 of Er3+ ions and 5F5->5I8 of Ho3+ ions. The threshold power density of radiation visualization of Tm3+:YAP-laser decreased with increasing concentration of Ho3+ ions and was 30 W/cm2 in the ZBLAN:1%Er3++1%Ho3+ sample. Keywords: Judd-Ofelt theory, up-conversion luminescence, visualization of IR radiation, fluoride glass, rare-earth elements.
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