Deformation of the crystal lattice during the formation of a spherulite microstructure in thin films of lead zirconate
Staritsyn M. V.1,2, Pronin V. P.3, Khinitch I. I.3, Kaptelov E. Y.1, Senkevich S. V.1, Pronin I. P.1, Nemov S. A.4
1Ioffe Institute, St. Petersburg, Russia
2Central Research Institute of Structural Materials Prometey, National Research Centre Kurchatov Institute, St. Petersburg, Russia
3Herzen State Pedagogical University of Russia, St. Petersburg, Russia
4Peter the Great Saint-Petersburg Polytechnic University, St. Petersburg, Russia
Email: Pronin.v.p@yandex.ru
The reversal of the crystal lattice during the formation of spherolite islands in thin films of lead zirconate-titanate is studied using scanning electron microscopy by diffraction of reflected electrons. It is shown that the lattice reversal in spherulites can occur both towards the center of the spherulite and towards its periphery. The mechanisms of formation and growth of spherulites are considered to explain the observed effect. Keywords: thin films of lead zirconate, CTS, rotational crystals, spherulite microstructure, reversal mechanisms.
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