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New Na2BaY4F16 matrix for up-conversion phosphors
Russian version
Volchek A. A. 1, Pominova D.V. 1,2, Alexandrov A.A. 1,3, Voronov V. V. 1, Volkov S. N. 4, Aksenov S. M. 4, Fedorov P. P. 1
1Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
2National Research Nuclear University “MEPhI”, Moscow, Russia
3Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
4Kola Science Centre of the Russian Academy of Sciences, Apatity, Russia
Email: angelina.vol4ek@yandex.ru, pominovavdv@gmail.com, alexandrov1996@yandex.ru, s.n.volkov@inbox.ru, aks.crys@gmail.com
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In the process of investigation of NaF-BaF2-YF3 system, a new phase Na2BaY4F16 (monoclinic crystal system, C2/m, Z=2, lattice parameters a= 12.1948(3) Angstrem, b=8.2486(2) Angstrem, c=7.0894(2)Angstrem, β= 119.893(3)o was prepared by solid-state synthesis. The first up-conversion luminescence studies have been carried out for Na2BaY4F16:Yb3+, Er3+ under excitation at 980 nm. The highest luminescence energy yield for Na2Ba(Y0.87Yb0.12Er0.01)4F16 was 5.5% at a pump power density of 1 W/cm2. Keywords: up-conversion phosphors, fluorides of rare-earth elements, barium fluoride, sodium fluoride.
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