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Microstructure and electrophysical properties of high-temperature 0.36BiScO3-0.64PbTiO3 piezoceramics
Russian version
Pankratiev P.A. 1, Smirnova E.P.1, Klimov V.N.2, Guk E. G. 1, Zaitseva N. V. 1, Sotnikov A. V. 3, Mukhin E. E. 1
1Ioffe Institute, St. Petersburg, Russia
2Central Research Institute of Structural Materials Prometey, National Research Centre Kurchatov Institute, St. Petersburg, Russia
3Emperor Alexander I St. Petersburg State Transport University, St. Petersburg, Russia
Email: pavel-pankratiev@yandex.ru
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Microstructure and properties of the 0.36BiScO3-0.64PbTiO3 (BSPT) ceramics produced by two different synthesis processes were studied. Ceramics with increased piezoeffect anisotropy (piezoelectric constants ratio d33/|d31|~5) was prepared. It was shown that modified two-step synthesis reduces the average grain size of ceramics from 8-10 μm to 0.8-1 μm. Considerable improvement of piezoelectric properties of the samples produced by a two step synthesis synthesis process (d33=525 pC/N) compared with a single-step process (d33=375 pC/N) is observed. Ceramics 0.36BiScO3-0.64PbTiO3 produced by the modified two-step process is a promising material for high temperature applications due to a high Curie temperature of TC=430 oC and improved piezoelectric properties. Keywords: BSPT, two-step synthesis, grain size, piezoelectric constants, piezoeffect anisotropy.
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