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Impurity paramagnetic centers in a single crystal of zinc tungstate doped with thulium
Russian version
Vazhenin V. A. 1, Potapov A. P. 1, Subbotin K. A. 2,3, Artyomov M. Yu. 1, Zimina Y. I. 2,3, Fokin A. V. 1, Titov A. N.2, Lis D. A. 2, Volkov P.A. 4
1Ural Federal University (Institute of Natural Sciences and Mathematics), Yekaterinburg, Russia
2Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
3Mendeleev University of Chemical Technology, Moscow, Russia
4National Research Center “Kurchatov Institute”, Moscow, Russia
Email: vladimir.vazhenin@urfu.ru, Alexander.Potapov@urfu.ru, soubbot1970@gmail.com, yulia_zimina@inbox.ru
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A thulium-doped ZnWO4 crystal grown by the Czochralski method was studied by using the EPR method at room temperature. Accidental impurities of paramagnetic ions Fe3+, Mn2+, Cr3+, and Gd3+ were found in the crystal. Trivalent ions are represented by both single monoclinic centers and triclinic dimeric associates. Spin Hamiltonians of all observed centers were constructed, providing a reasonably good description of the experimental results. The concentration ratios of these centers were also estimated. Keywords: zinc tungstate, impurity ions, iron group, REE, paramagnetic resonance.
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