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Parity effect --- symmetry of n-alkanes molecules
Russian version
Borisov A. K. 1, Marikhin V. A. 1, Egorov V. M. 1
1Ioffe Institute, St. Petersburg, Russia
Email: borisov.ak@mail.ioffe.ru
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The features of phase transitions in the homologous series of normal alkanes of different parities have been studied. The real values of thermodynamic parameters were obtained as a result of eliminating the methodological errors of differential scanning calorimetry. The presence of a parity effect in the homologous series of n-alkanes was revealed both in the behavior of the thermodynamic parameters of phase transitions and in the process of structural rearrangement of crystallographic packing during the solid-solid phase transition, caused by different symmetries of n-alkane molecules. Keywords: n-alkanes, molecular crystals, molecular packing, symmetry, phase transitions, differential scanning calorimetry, parity effect.
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