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Paramagnetic resonance of Fe3+ and Cu2+ centers in yttrium orthosilicate doped with iron
Artyomov M. Yu.
1, Potapov A. P.
1, Soubbotin K. A.
2,3, Vazhenin V. A.
1, Titov A. I.
2, Fokin A. V.1, Pavlov S. K.2,3, Lis O. N.2
1Ural Federal University (Institute of Natural Sciences and Mathematics), Yekaterinburg, Russia
2Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
3Mendeleev University of Chemical Technology, Moscow, Russia
2Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
3Mendeleev University of Chemical Technology, Moscow, Russia
Email: soubbot@lsk.gpi.ru, anatoly.titov.4@gmail.com, sergey.pavlov97@mail.ru
Two Fe3+ centers, as well as the spectrum of an uncontrolled Cu2+ impurity, were studied using paramagnetic resonance in a specially grown Y2SiO5 : Fe crystal. The parameters of spin Hamiltonians are determined both in laboratory and local (with diagonal second-rank fine structure tensor or hyperfine interaction tensor A) coordinate systems. The localization of Fe3+, Cr3+, Gd3+ and Cu2+ centers in yttrium and scandium silicates is discussed. Keywords: orthosilicates, impurity ions, paramagnetic resonance.
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