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Raman and Photoluminescence Spectra for Yb and Lu doped the Strontium Zirconate SrZrO3
Russian version
Shkerin S.N.1, Pavlovich A.V.1, Abdurakhimova R.K. 1, Yaroslavtseva T.V. 2, Ul’yanova E. S. 2
1Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia
2Institute of Solid State Chemistry, Russian Academy of Sciences, Ural Branch, Yekaterinburg, Russia
Email: shkerin@mail.ru, nastenka_98@mail.ru, arianaboimuradova@yandex.ru, tanya_yaroslavtseva@mail.ru, tsivileva.yekaterina@yandex.ru
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Raman spectra equipment with different wavelengths (532 and 785 nm) was used for investigation of derivatives based on strontium zirconate. A number of reflexes independent of the laser wavelength are identified as the structure related. Sr-O vibration observed at 93 cm-1 is previously discussed in detail in the literature and it is generally accepted that it realizes at the smallest wave numbers. The presence of the 59 cm-1 structure band is shown at first time. It is interpreted as manifestation of vibration of a heavy cation in the strontium position (LuSr)-O. Reflexes that depend on the laser wavelength are considered as related to luminescence. It was evidenced an oxygen vacancies self-manifestation by luminescence using the dependence of line intensity on material composition. It was first time observed for materials with perovskite structure in this study. Keywords: Perovskite structure, SrZrO3, Raman spectroscopy, pointe defects associates luminescence.
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