Eremin E. V.1, Gudim I. A.1, Titova V. R.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Email: aalexanderr@mail
A comparative analysis of magnetic properties of gadolinium ferroborates GdFe3(BO3)4 grown from three different solvents: lithium tungstate [GdFe3(BO3)4], trimolybdate-bismuth [GdFe3(BO3)4 : Bi] and potassium-molybdate [GdFe3(BO3)4 : Mo] melt solutions has been carried out. Phase diagrams of the magnetic state "temperature - magnetic field" of the investigated crystals have been constructed. It is shown that GdFe3(BO3)4 does not contain uncontrolled impurities, whereas for GdFe3(BO3)4 : Bi the incorporation of uncontrolled Bi3+ impurities in small amounts (~ 6 at.%) is confirmed. For GdFe3(BO3)4 : Mo, it was assumed that both Mo ions (of valence higher than 3+) and potassium ions K+ are present as uncontrolled impurities. Keywords: antiferromagnetics, multiferroics, spin reorientation transition.
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