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Home » Optics and Spectroscopy » Year 2023, issue 4 » Article p. 419
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Luminescence of manganese and chromium ions in spinel hosts
Russian version
DOI: 10.61011/EOS.2023.04.56350.56-22
Khaidukov N.M. 1, Brekhovskikh M.N. 1, Kirikova N. Yu. 2, Kondratyuk V.A. 2, Makhov V.N. 2
1Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
2Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russia
Email: khaiduk2@gmail.com, mbrekh@igic.ras.ru, kirikovany@lebedev.ru, valentin.kondratuk@mail.ru, makhovvn@lebedev.ru
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Single-phase ceramic samples of MgAl2O4, ZnAl2O4 and LiAl5O8 spinels containing manganese or chromium ions have been synthesized by a high-temperature solid-state reactions method. It has been shown that the luminescence properties of the synthesized phosphors, in particular, the appearance of intense red luminescence from Mn4+ ions, as well as the magnitude of inhomogeneous line broadening in the luminescence spectra of Mn4+ and Cr3+ ions depend on the degree of cation inversion, which provides the charge compensation for stabilizing Mn4+ ions in the octahedral sites of the spinel structures upon the substitution of Al3+ ions, simultaneously resulting in disordered spinel crystal structures. Keywords: spinel, inversion, manganese and chromium ions, red phosphor.
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