Physics of the Solid State
Volumes and Issues
Lattice dynamics and phase transitions in a crystal Ba2ZnTeO6
Zinenko V. I.1, Shinkorenko A. S.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Email: shas@iph.krasn.ru

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The lattice dynamics of Ba2ZnTeO6 double perovskite in three phases has been studied. Vibrational spectra and dynamic charges are calculated. In the rhomobohedral phase R3m, soft modes were found; after their condensation, the C2/m phase was obtained, which agrees with the experiment. An assessment was made of the dependence of the enthalpy of different phases on pressure; it showed that the monoclinic phase is more favorable at 0 pressure, but as the pressure increases to 2.9 GPa, the cubic phase Fm3m becomes advantageous. Keywords: Lattice dynamics, phase transitions, double perovskites.
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