Physics of the Solid State

To authors

Volumes and Issues

2023
- 1 2 3 4 5 6 7 8 9 10 11 12
2022
- 1 2 3 4 5 6 7 8 9 10 11 12 13 14

First-order phase transition in nanotubular titanium dioxide

Russian version

DOI: 10.21883/PSS.2022.14.54324.17s

Sushnikova A.A.^1,2, Valeeva A. A. ^2,3, Dorosheva I.B.^1,2, Rempel A.A. ^1,2

¹Institute of Metallurgy of Ural Branch of the Russian Academy of Science, Ekaterinburg, Russia
²Ural Federal University after the first President of Russia B.N. Yeltsin, Yekaterinburg, Russia
³Institute of Solid State Chemistry, Russian Academy of Sciences, Ural Branch, Yekaterinburg, Russia

Email: sushnikova.ann@gmail.com, anibla_v@mail.ru, i.b.dorosheva@urfu.ru, rempel.imet@mail.ru

PDF

Abstract
References
Статистика просмотров

Titanium dioxide (TiO₂) nanotubes array with the length of 16 μm and the outer diameter of 100 nm were synthesized by anodic oxidation of titanium foil in an electrolyte solution containing a fluorine-containing solution of ethylene glycol. The selected synthesis conditions make it possible to separate the nanotubular array from the titanium foil and study it as a homogeneous functional material. The performed scanning electron microscopy study and Brunauer-Emmett-Teller analysis allowed to get data on the morphology of the samples. X-ray diffraction, thermogravimetric, and differential scanning calorimetry analysis made it possible to determine the temperature of the phase transition of the amorphous state into crystalline anatase (sp.gr. I4/amd). Observed phase transition of first order takes place at temperature about 350^oC. Keywords: nanotubular titanium dioxide films, anodic oxidation, phase transition, anatase, TG, DSC.

A.A. Rempel, A.A. Valeeva, A.S. Vokhmintsev, I.A. Weinstein. Russ. Chem. Rev. 90 (2021). DOI: 10.1070/RCR4991
T.S Natarajan, K. Natarajan, H.C. Bajaj, R.J. Tayade. Ind. Eng. Chem. Res. 50, 13, 7753 (2011)
A.V. Volkov, V.V. Polyanskaya, M.A. Moskvina, S.B. Zezin, A.I. Dementev, A.L. Volynskii, N.F. Bakeev. Nanotechnol. Russ. 7, 7, 377 (2012)
A.A. Valeeva, I.B. Dorosheva, E.A. Kozlova, R.V. Kamalov, A.S. Vokhmintsev, D.S. Selishchev, A.A. Saraev, E.Yu. Gerasimov, I.A. Weinstein, A.A. Rempel. J. Alloys Compd. 796, 293 (2019)
A.A. Valeeva, E.A. Kozlova, A.S. Vokhmintsev, R.V. Kamalov, I.B. Dorosheva, A.A. Saraev, I.A. Weinstein, A.A. Rempel. Sci. Rep. 8, 1, 9607 (2018)
A.A. Valeeva, I.B. Dorosheva, E.A. Kozlova, A.A. Sushnikova, A.Y. Kurenkova, A.A. Saraev, H. Schroettner, A.A. Rempel. Int. J. Hydrogen Energy 46, 32, 16917 (2021)
A.S. Vokhmintsev, I.A. Weinstein, R.V. Kamalov, I.B. Dorosheva. Bull. Russ. Acad. Sci.: Phys. 78, 9, 932 (2014)
W. Li, T. Bak, A. Atanacio, J. Nowotny. Appl. Catal. B 198, 243 (2016)
D. v Svadlak, J. Shanelova, J. Malek, L.A. Perez-Maqueda, J. Manuel Criado, T. Mitsuhashi. Thermochim. Acta 414, 137 (2004)
S.A. Mansour. Ceram. Int. 45, 2, 2893 (2019)
Z. Baolong, C. Baishun, Sh. Keyu, H. Shangjin, L. Xiaodong, D. Zongjie, Ya. Kelian. Appl. Catal. B 40, 253 (2003)
C.G. Silva, J.Lu. Faria. Photochem. Photobiol. Sci. 8, 705 (2009)
X. Wang, Li-Li Wang, D. Guo, Lu-Lu Ma, Ba. Zhu, P. Wang, G. Wang, Shou-Min Zhang, W. Huang. Catal. Today 327, 182 (2019)
Z. Xu, S. Wang, C. Ma, K. Luo, F. Fang. Phys. Status Solidi A 216, 6, 1800836 (2019)
J. Liao, S. Lin, N. Pan, S. Li, X. Cao, Ya. Cao. Mater. Charact. 66, 24 (2012)
S. Villa, V. Caratto, F. Locardi, S. Alberti, M. Sturini, Andrea, F.Maraschi, F. Canepa, M. Ferretti. Mater. 9, 771 (2016)
H. Xie, Q. Zhang, T. Xi, J. Wang, Ya. Liu. Thermochim. Acta 381, 45 (2002)

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Institute Officers:

Contact us: