Physics of the Solid State
Volumes and Issues
Synthesis, crystal structure and high-temperature heat capacity of substituted apatites Pb9R(GeO4)3(VO4)3 (R=Tb, Dy, Ho)
Denisova L. T.1, Molokeev M. S.1,2, Golubeva E. O.1, Belousova N. V.1, Denisjv V. M.1
1Siberian Federal University, Krasnoyarsk, Russia
2Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Email: ldenisova@sfu-kras.ru

PDF
Pb9R(GeO4)3(VO4)3 (R=Tb, Dy, Ho) apatites were obtained by solid-phase synthesis from the initial oxides of PbO, Tb2O3 (Dy2O3, Ho2O3), GeO2 and V2O5 by sequential annealing (at a temperature of 773-1073 K) in an air atmosphere. Their crystal structure has been determined by X-ray diffraction analysis. The high-temperature heat capacity was measured by differential scanning calorimetry. Based on the experimental dependence of the heat capacity on the temperature, the thermodynamic properties are calculated. Keywords: apatites, solid-phase synthesis, crystal structure, heat capacity, thermodynamic properties. Keywords: apatites, solid-phase synthesis, crystal structure, heat capacity, thermodynamic properties.
  1. T. Kanazawa. Neorganicheskiye fosfatnyye materialy. Nauk. dumka, Kiev (1998). 298 s. (in Russian)
  2. D. Grossin, S. Rollin-Martinet, C. Estournis, F. Rossignol, E. Champion, C. Comdes, C. Rey, C. Geoffroy, C. Drouet. Acta Biomater. 6, 2, 577 (2010)
  3. Sh.Yu. Azimov, A.A. Ismatov, N.F. Fedorov. Apatity i ikh redkozemelnyye analogi. FAN, Tashkent (1990). 116 s. (in Russian)
  4. T. Yano, Y. Nabeta, A.A. Watanabe. Appl. Phys. Lett. 18, 12, 570 (1971)
  5. L. Kovacs, A. Peter, M. Gospodinov, R. Capelletti. Phys. Status Solidi C 2, 1, 689 (2005)
  6. J. Zhang, H. Liang, H. Yu, Q. Su. Mater. Chem. Phys. 114, 242 (2009)
  7. S. Kale, S. Kahaudal, S. Disale, R. Jayaram. Curr. Chem. Lett. 1, 69 (2012)
  8. S.V. Dobrydnev, M.Yu. Molodtsova. Izv. TulGU. Estestv. nauki. 1, 1, 212 (2014) (in Russian)
  9. M. Manecki, P.A. Mourice, S.J. Traina. Am. Mineral. 85, 932 (2000)
  10. A.V. Ignatov, T.M. Savankova, E.G. Didorenko, A.Yu. Talykova, E.I. Getman, L.V. Pasechnik. Vestn. Donetskogo nats. un-ta, Ser. A. Estestv. nauki. 1, 152 (2014) (in Russian)
  11. T.M. Savankova, L.G. Akselrud, L.I. Ardanova. J. Chem. 6, 1 (2014)
  12. M. Pasero, A.R. Kampf, C. Ferraris, I.V. Pekov, J. Rakovan, T.J. White. Eur. J. Mineral. 22, 163 (2010)
  13. V.D. Zhuravlev, Yu.A. Velikodny. ZhNKh 54, 10, 1626 (2009) (in Russian)
  14. T. Baikie, S.S. Pramada, C. Ferraris. Acta Crystallogr. B 66, 1 (2010)
  15. N. Lakshminarasimhan, U.V. Varadaraju. J. Solid State Chem. 178, 3284 (2005)
  16. H. Benmoussa, M. Mikou, A. Bensaoud. Mater. Res. Bull. 35, 369 (2000)
  17. S. Nakayama, Y. Higuchi, Y. Kondo. Solid State Ion. 170, 219 (2004)
  18. N.V. Yablochkova. ZhNKh 58, 7, 219 (2004) (in Russian)
  19. L.T. Denisova, A.D. Izotov, Yu.F. Kargin, V.M. Denisov, N.A. Galiakhmetova. DAN 477, 3, 313 (2017) (in Russian)
  20. L.T. Denisova, Yu.F. Kargin, N.V. Belousova, N.A. Galiakhmetova, V.M. Denisov. Neorgan. materialy 54, 2, 177 (2018) (in Russian)
  21. L.T. Denisova, E.O. Golubeva, N.V. Belousova, V.M. Denisov, N.A. Galiakhmetova. FTT 61, 7, 1397 (2019) (in Russian)
  22. L.T. Denisova, Yu.F. Kargin, E.O. Golubeva, N.V. Belousova, V.M. Denisov. Neorgan. materialy 55, 2, 182 (2019) (in Russian)
  23. L.T. Denisova, Yu.F. Kargin, E.O. Golubeva, G.M. Zeer, A.K. Abkaryan, V.M. Denisov. Neorgan. materialy 56, 10, 1081 (2020) (in Russian)
  24. L.T. Denisova, M.S. Molokeev, A.A. Aleksandrovsky, Yu.F. Kargin, E.O. Golubeva, V.M. Denisov. Neorgan. materialy 57, 11, 1226 (2021) (in Russian)
  25. L.T. Denisova, E.O. Golubeva, V.M. Denisov, N.V. Belousova, L.G. Chumilina. Russ. J. Phys. Chem. A 94, 13, 2669 (2020)
  26. L.T. Denisova, M.S. Molokeev, V.M. Denisov, E.O. Golubeva, N.A. Galiakhmetova. FTT 62, 11, 1828 (2020) (in Russian)
  27. V.K. Karzhavin. Termodinamicheskiye velichiny khimicheskikh elementov. Primery ikh prakticheskogo primeneniya. Izd-vo Kolskogo nauch. tsentra RAN, Apatity (2011). 160 s. (in Russian)
  28. V.V. Bogach, S.B. Dobrydnev, V.S. Beskov. ZhNKh 46, 7, 1127 (2001) (in Russian)
  29. Bruker AXS TOPAS V4: General profile and structure analysis software for powder diffraction data. --- User's Manual. Bruker AXS, Karlsruhe, Germany (2008)
  30. L.T. Denisova, L.A. Irtyugo, Yu.F. Kargin. Neorgan. materialy. 53, 1, 71 (2017) (in Russian)
  31. S.A. Ivanov. ZhSKh 31, 4, 80 (1990) (in Russian)
  32. S.A. Ivanov, V.E. Zavodnik. Kristallografiya 34, 4, 824 (1989) (in Russian)
  33. T.M. Savankova, A.V. Ignatyev, D.M. Utochkin. Naukovi pratsi DonNTU. Ser. Khim. khim. tekhn. Vip. 3 (23), 78 (2014) (in Russian)
  34. E.I. Getman, N.V. Yablochkova, S.N. Loboda, L.V. Karakay. Vestn. Don. nats. un-ta. Ser. A. Estestv. nauki 1, 129 (2013) (in Russian)
  35. E.I. Get'man, N.V. Yablochkova, S.N. Loboda, V.V. Prisedsky, V.P. Antonovich, N.A. Chivireva. J. Solid State Chem. 181, 2386 (2008)
  36. V.S. Urusov, V.O. Khudolozhkin. Geokhimiya 10, 1509 (1974) (in Russian)
  37. S.P. Yatsenko, E.G. Fedorova. Redkozemelnye elementy. Vzaimodeistiviye s p-metallami. Nauka, M. (1990). 280 s. (in Russian)
  38. A.V. Knotko, I.A. Presnyakov, Yu.D. Tretyakov. Khimiya tverdogo tela. Akademiya, M. (2006). 304 s. (in Russian)

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245
E-mail: post@mail.ioffe.ru