Structural and Dielectric Properties of Bi3Ti1.5W0.5O9
Zubkov S. V.1, Parinov I. A.2, Kuprin Yu. A.1, Nazarenko A. V.3
1Scientific Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia
2Vorovich Institute of Mathematics, Mechanics and Informatics, Southern Federal University, Rostov-on-Don, Russia
3Federal Research Center Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, Russia
Email: svzubkov61@mail.ru

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Layered perovskite-like oxide Bi3Ti1.5W0.5O9 has been synthesized by the method of high-temperature solid-state reaction. The X-ray diffraction study showed that the compound is single-phase and has the structure of the family of Aurivillius phases (AP) with parameters close to the orthorhombic unit cell corresponding to the space group A21am. The temperature dependences of the relative permittivity ε/ε0 and the loss tangent tgsigma are measured at different frequencies. For the synthesized compound, the piezoelectric modulus d33 was measured. The microstructure of Bi3Ti1.5W0.5O9 has been obtained. Keywords: Aurivillius phases, Bi3Ti1.5W0.5O9, activation energy Ea, Curie temperature TC, piezoelectric modulus d33.
  1. B. Aurivillius. Arkiv. Kemi. 54, 463 (1949)
  2. B. Aurivillius. Arkiv. Kemi. 58, 499 (1949)
  3. B. Aurivillius. Arkiv. Kemi. 37, 512 (1950)
  4. G.A. Smolensky, V.A. Isupov, A.I. Agranovskaya. Physics of the Solid State 1, 169 (1959)
  5. I.G. Ismailzade. Izv. AN SSSR 24, 1198 (1960) (in Russian)
  6. B. Aurivillius. Phys. Rev. 12, 6893 (1962)
  7. E.C. Subbarao. Am. Ceram. Soc. 45, 166 (1962)
  8. E.C. Subbarao. Chem. Phys. 34, 695 (1961)
  9. E.C. Subbarao. Phys. Rev. 122, 804 (1961)
  10. E.C. Subbarao. Phys. Chem. Solids 23, 665 (1962)
  11. S.V. Zubkov, V.G. Vlasenko. Physics of the Solid State 59, 2325 (2017)
  12. S.V. Zubkov, S.I. Shevtsova. Adv. Mater. 6, 173 (2020)
  13. T. Kikuchi. J. Less-Common Met. 48, 319 (1976)
  14. Neil C. Hyatt, Ian M. Reaney, S. Kevin Knight. Phys. Rev. B 71, 024119 (2005)
  15. W. Kraus, G. Nolze. PowderCell for Windows. Version 2.3. Federal Institute for Materials Research and Testing, Berlin, (1999)
  16. V.A. Isupov. Journal of Inorganic Chemistry 39, 5, 731 (1994)
  17. V.A. Isupov. Ferroelectrics 189, 211 (1996)
  18. V.A. Isupov. Neorgan. materialy 421, 353 (2006) (in Russian)
  19. V.M. Goldschmidt. Geochemische Verteilungsgesetze der Elemente. Norske, Oslo (1927)
  20. R.D. Shannon. Acta Crystallogr. A 32, 75 (1976)
  21. Shi Luo, Y. Noguchi, M. Miyayama, T. Kubo. Mater. Res. Bull. 36, 531 (2001)

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