Volumes and Issues
Home » Optics and Spectroscopy » Year 2022, issue 1 » Article p. 115
<<<>>>
Role of LMCT states in luminescence excitation processes in europium indolecarboxylates
Russian version
DOI: 10.21883/EOS.2022.01.52996.26-21
Tsaryuk V. I.1, Zhuravlev K. P.1
1Fryazino Branch, Kotel’nikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences, Fryazino, Moscow oblast, Russia
Email: vtsaryuk@mail.ru, kpz225@mail.ru
PDF
The luminescence excitation energy transfer in europium and terbium indole-3-carboxylates, indole-3-acetates and indole-3-propionates as well as ternary indolecarboxylates containing 1,10-phenanthroline and 2,2'-bipyridine molecules have been studied. The luminescence excitation spectra, the lifetimes of the 5D0 (Eu3+) and 5D4 (Tb3+) states, and the luminescence intensity are analyzed. The decisive role of ligand-metal charge transfer (LMCT) states in the quenching of the luminescence of europium aromatic carboxylates containing a π-excessive pyrrole or indole fragment is demonstrated. Most europium compounds are characterized by quenching due to the depopulation of the 5D0 state of the Eu3+ ion through the low-energy LMCT state. But in some ternary compounds, the LMCT state being of higher energy participates in the nonradiative depopulation of the excited electronic states of the ligand. Keywords: luminescence, Eu3+, Tb3+, LMCT, indolecarboxylate, π-excessive heterocycle.
  1. G.F. de Sa, O.L. Malta, C. de Mello Donega, A.M. Simas, R.L. Longo, P.A. Santa-Cruz, E.F. da Silva Jr. Coord. Chem. Rev., 196 (1), 165 (2000). DOI: 10.1016/S0010-8545(99)00054-5
  2. G.K. Liu, M.P. Jensen, P.M. Almond. J. Phys. Chem. A., 110 (6), 2081 (2006). DOI: 10.1021/jp0558674
  3. S. Petoud, J.-C.G. Bunzli, T. Glanzman, C. Piguet, Q. Xiang, R.P. Thummel. J. Lumin., 82 (1), 69 (1999). DOI: 10.1016/S0022-2313(99)00015-0
  4. W.M. Faustino, O.L. Malta, G.F. de Sa. J. Chem. Phys., 122, 054109 (2005). DOI: 10.1063/1.1830452
  5. W.M. Faustino, O.L. Malta, G.F. de Sa. Chem. Phys. Lett., 429 (4-6), 595 (2006). DOI: 10.1016/j.cplett.2006.08.059
  6. D.V. Lapaev, V.G. Nikiforov, V.S. Lobkov, A.A. Knyazev, Yu.G. Galyametdinov. Opt. Mater., 75, 787 (2018). DOI: 10.1016/j.optmat.2017.11.042
  7. K. Yanagisawa, Y. Kitagawa, T. Nakanishi, T. Seki, K. Fushimi, H. Ito, Y. Hasegawa. Chem. Eur. J., 24 (8), 1956 (2018). DOI: 10.1002/chem.201705021
  8. V.I. Tsaryuk, K.P. Zhuravlev. J. Lumin., 237, 118159 (2021). DOI: 10.1016/j.jlumin.2021.118159
  9. V. Tsaryuk, K. Zhuravlev, V. Kudryashova, V. Zolin, J. Legendziewicz, I. Pekareva, P. Gawryszewska. J. Photochem. Photobiol. A: Chem., 197 (2-3), 190 (2008). DOI: 10.1016/j.jphotochem.2007.12.022
  10. K.P. Zhuravlev, . Michnik, P. Gawryszewska, V.I. Tsaryuk, V.A. Kudryashova. Inorg. Chim. Acta., 492, 1 (2019). DOI: 10.1016/j.ica.2019.04.014
  11. A. Tine, P. Valat, J.J. Aaron. J. Lumin., 36 (2), 109 (1986). DOI: 10.1016/0022-2313(86)90059-1
  12. A.K. Solanki, A.M. Bhandari. J. Inorg. Nucl. Chem., 41 (9), 1311 (1979). DOI: 10.1016/0022-1902(79)80045-7
  13. F.-Y. He, L. Wang, Zh. Chen, J. Wu. Synth. React. Inorg. Met.-Org. Chem., 24 (4), 575 (1994). DOI: 10.1080/00945719408000134
  14. G.-L. Law, K.-L. Wong, K.-K. Lau, H.-L. Tam, K.-W. Cheah, W.-T. Wong. Eur. J. Inorg. Chem., 2007 (34), 5419 (2007). DOI: 10.1002/ejic.200700584
  15. Z.-N. Wang, X.-T. Xu, X. Lv, F.-Y. Bai, S.-Q. Liu, Y.-H. Xing. RSC Adv., 5 (126), 104263 (2015). DOI: 10.1039/C5RA19376A
  16. Y. Shimazaki, T. Yajima, M. Takani, O. Yamauchi. Coord. Chem. Rev., 253 (3-4), 479 (2009). DOI: 10.1016/j.ccr.2008.04.012
  17. V. Viossat, P. Lemoine, E. Dayan, N.-H. Dung, B. Viossat. J. Mol. Struct., 741 (1-3), 45 (2005). DOI: 10.1016/j.molstruc.2005.01.040
  18. B. Morzyk-Ociepa. Vibr. Spectrosc., 49 (1), 68 (2009). DOI: 10.1016/j.vibspec.2008.04.014
  19. K. Szmigiel-Bakalarz, A. Skoczynska, M. Lewanska, D. Gunther, O. Oeckler, M. Malik-Gajewska, D. Michalska, B. Morzyk-Ociepa. Polyhedron., 185, 114582 (2020). DOI: 10.1016/j.poly.2020.114582
  20. M. Cinar, M. Karabacak, A.M. Asiri. Spectrochim. Acta A., 137, 670 (2015). DOI: 10.1016/j.saa.2014.08.090
  21. X.-J. Deng, Q. Yu, H.-D. Bian, H.-D. Ju, B.-L. Wang. Trans. Met. Chem., 41, 591 (2016). DOI: 10.1007/s11243-016-0057-0
  22. T.V. Sravanthi, S.L. Manju. Eur. J. Pharm. Sci., 91, 1 (2016). DOI: 10.1016/j.ejps.2016.05.025
  23. A. Kumari, R.K. Singh. Bioorg. Chem., 89, 103021 (2019). DOI: 10.1016/j.bioorg.2019.103021
  24. R.K. Bauer, P. de Mayo, W.R. Ware, K.C. Wu. J. Phys. Chem., 86 (19), 3781 (1982). DOI: 10.1021/j100216a016
  25. A. Tine, Ph. Guillaume, A. Massat, J.-J. Aaron. Spectrochim. Acta A., 54 (10), 1451 (1998). DOI: 10.1016/S1386-1425(98)00046-8
  26. K. Zhuravlev, V. Tsaryuk, V. Kudryashova, I. Pekareva, J. Sokolnicki, Yu. Yakovlev. J. Lumin., 130 (8), 1489 (2010). DOI: 10.1016/j.jlumin.2010.03.018
  27. M.H.V. Werts, R.T.F. Jukes, J.W. Verhoeven. Phys. Chem. Chem. Phys., 4 (9), 1542 (2002). DOI: 10.1039/B107770H
  28. V.I. Tsaryuk, K.P. Zhuravlev, A.V. Vologzhanina, V.A. Kudryashova, V.F. Zolin. J. Photochem. Photobiol. A: Chem., 211 (1), 7 (2010). DOI: 10.1016/j.jphotochem.2010.01.012
  29. F.R. Gon calves e Silva, R. Longo, O.L. Malta, C. Piguet, J.-C.G. Bunzli. Phys. Chem. Chem. Phys., 2 (23), 5400 (2000). DOI: 10.1039/B005624N
  30. K.P. Zhuravlev, V.I. Tsaryuk, V.A. Kudryashova. J. Fluorine Chem., 212, 137 (2018). DOI: 10.1016/j.jfluchem.2018.06.002
  31. Sverdlova O.V. Elektronnye spektry v organicheskoy khimii. (Leningrad "Khimiya", Leningradskoe otd., 1985) (in Russian)
  32. V.F. Zolin, L.N. Puntus, V.I. Tsaryuk, V.A. Kudryashova, J. Legendziewicz, P. Gawryszewska, R. Szostak. J. Alloys Compd., 380 (1-2), 279 (2004). DOI: 10.1016/j.jallcom.2004.03.055

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245
E-mail: post@mail.ioffe.ru