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Transmission spectra of singe crystals of MAPbI3 hybrid perovskites near the edge of fundamental absorption
Russian version
DOI: 10.21883/EOS.2022.01.52995.21-21
Anikeeva V. E. 1,2, Boldyrev K. N. 1,2, Semenova O. I. 3, Popova M. N. 1
1Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russia
2National Research University Higher School of Economics, Moscow, Russia
3Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: vanikeeva@hse.ru, kn.boldyrev@gmail.com, oisem@isp.ncs.ru, popova@isan.troitsk.ru
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The paper presents the transmission spectra of hybrid perovskite MAPbI3 single crystals near the fundamental absorption edge in a wide temperature range. The absorption coefficient α of the single crystal samples is estimated at a temperature T = 150 K for the light with a photon energy E = 1.6 eV and at T = 40 K for E = 1.8 eV. The obtained values turned out to be several orders of magnitude smaller than the values of α for thin-film samples known from the literature. A sharp shift of the fundamental absorption edge by ~ 100 meV was observed at a temperature T1 =160 K of the structural phase transition from the tetragonal to the orthorhombic phase. The temperature hysteresis of the shift of the fundamental absorption edge near T1 was recorded, which is characteristic of a first-order phase transition. Keywords: hybrid organometallic perovskites, MAPbI3 single crystal, optical spectroscopy, fundamental absorption.
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