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Spectral-luminescence properties of ZrO2-Sc2O3-Tb2O3 crystals
Russian version
DOI: 10.21883/EOS.2022.01.52991.20-21
Batygov S. Kh. 1, Borik M. A. 1, Kulebyakin A. V. 1, Larina N.A. 2, Lomonova E. E. 1, Myzina V. A. 1, Ryabochkina P. A. 2, Sidorova N. V. 2, Taratynova A. D. 2, Tabachkova N. Yu. 1,3
1Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
2Ogarev Mordovian State University, Saransk, Russia
3National University of Science and Technology MISiS, Moscow, Russia
Email: sbat@lst.gpi.ru, borik@lst.gpi.ru, kulebyakin@lst.gpi.ru, saharova.1996@mail.ru, lomonova@lst.gpi.ru, vamyzina@lst.gpi.ru, ryabochkina@freemail.mrsu.ru, ya.natalka2112@yandex.ru, alina.taratynova@mail.ru, ntabachkova@gmail.com
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Crystals of the concentration series ZrO2-(8-10) mol.% Sc2O3-(1-2) mol.% Tb2O3 were grown by the method of directional crystallization of the melt from a cold container. Analysis of the spectral-luminescence characteristics of these crystals after growth and after annealing processing in a vacuum revealed the presence of both Tb3+ and Tb4+ ions in them. In crystals ZrO2-(8-10) mol.% Sc2O3-(1-2) mol.% Tb2O3, the presence of a process of non-radiative energy transfer from Tb4+ ions to Tb3+ ions was revealed. Keywords: solid solutions of zirconium dioxide, luminescence, terbium ions.
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