Krylov A. S.
1, Vtyurin A. N.
1,2, Gudim I. A.
1, Nemtsev I. V.
1,2,3, Krylova S. N.
11Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2Siberian Federal University, Krasnoyarsk, Russia
3Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia
Email: shusy@iph.krasn.ru, vtyurin@iph.krasn.ru, slanky@iph.krasn.ru
The Raman spectra of four crystals of TbFe3-xGax(BO3)4 solid solutions (x from 0 to 0.54) were studied in the temperature range from 8 to 350 K. The temperatures of structural phase transitions were determined. The observed spectral behavior is characteristic to condensation and restoration of soft modes. Soft modes are associated with a structural phase transition from the R32 phase to the P3121 phase. The Compositions-Temperature phase diagram was constructed. Keywords: Raman spectroscopy, temperature dependence, soft modes, ferroborates, phase diagramm.
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