Gureva S. A.
1, Marikhin V. A.
1, Borisov A. K.
1, Vlasova E. N.
21Ioffe Institute, St. Petersburg, Russia
2Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia
Email: swet.gurjewa@gmail.com
An analysis of absorption band progressions in the IR spectrum of monodisperse tricosane n-C23H48 was conducted. Dispersion curves were obtained for the absorption band progressions of the rocking vibrations of CH2 groups and the stretching (skeletal) vibrations of C-C bonds. The interaction parameters of the studied vibrations were determined based on the coupled oscillator model in the selected regions corresponding to the approximation of interaction between the nearest neighbors. For the first time, it was established that the interaction parameters of the vibrations depend significantly on the magnitude of the phase shift. Keywords: n-alkanes, IR spectroscopy, absorption band progressions, coupled oscillator model.
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