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Effects of Sm3+ ions modification on the structure and properties of 0.36(Bi1-xSmx)ScO3-0.64PbTiO3
Russian version
Hook Is. G.1, Smirnova Is. N.1, Klimov V. N.2, Pankratiev N. A.1, Zaytseva N. V.1, Mukhin Is.Is.1
1Ioffe Institute, St. Petersburg, Russia
2Central Research Institute of Structural Materials Prometey, National Research Centre Kurchatov Institute, St. Petersburg, Russia
Email: elgrguk@gmail.com
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Effect of the modification by Sm3+ ions on the properties of the solid solution 0.36(Bi1-xSmx)ScO3-0.64PbTiO3 (BSSPT) with x=0.022, 0.038, 0.056 was studied. The veriants of modification such as stoichiometrical, superstoichiometrical, and excess doping after calcination as well as sintering techniques (one-step, two-step) were performed. The crystal structure, elemental composition, dielectric properties and piezoelectric constant d33 were measured. BSSPT is shown to be single-phase and it has a tetragonal (P4mm) perovskite structure. The elemental composition of all variants of the synthesized BSSPT ceramics demonstrates the almost identical samarium content, including the Sm3+ ion doping into the A sublattice of the ceramics perovskite structure ABO3 after calcination. The maximum value of the dielectric constant εm and the corresponding temperature Tm decrease with increasing the Sm3+ ion concentration. The obtained maximum d33 value was 536 pC/N, which exceeds d33=525 pC/N for unmodified 0.36BiScO3-0.64PbTiO3. Keywords: piezoelectric ceramics, modification, microstructure, dielectric properties, piezoelectric properties.
  1. R.E. Eitel, C.A. Randall, T.R. Shrout, S.-E. Park. Jpn. J. Appl. Phys. 41, 4R, 2099 (2002)
  2. T. Zou, X. Wang, W. Zhao, L. Li. J. Am. Ceram. Soc. 9, 1, 121 (2008)
  3. E.G. Guk, E.P. Smirnova, V.N. Klimov, P.A. Pankrat'ev, N.V. Zaitseva, A.V. Sotnikov, E.E. Mukhin. FTT 66, 8, 1397 (2024). (in Russian)
  4. E.P. Smirnova, V.N. Klimov, E.G. Guk, P.A. Pankrat'ev, N.V. Zaitseva, A.V. Sotnikov, E.E. Mukhin. FTT 65, 11, 1971 (2023). (in Russian)
  5. E.P. Smirnova, V.N. Klimov, E.G. Guk, P.A. Pankrat'ev, N.V. Zaitseva, A.V. Sotnikov, E.E. Mukhin. FTT 66, 1, 103 (2024). (in Russian)
  6. J. Cheng, R. Eitel, N. Li, L.E. Cross. J. Appl. Phys. 94, 1, 605 (2003)
  7. Q. Zhang, Z. Li, F. Li, Z. Xu, X. Yao. J. Am. Ceram. Soc. 93, 10, 3330 (2010)
  8. I. Sterianou, D.C. Sinclair, I.M. Reaney, T.P. Comyn, A.J. Bell. J. Appl. Phys. 106, 8, 084107 (2009)
  9. Y. Dong, K. Zhao, Z. Zhou, R. Wang. J. Am. Ceram. Soc. 105, 11, 6898 (2022)
  10. S.J. Zhang, R.E. Eitel, C.A. Randall, T.R. Shrout, E.F. Alberta. Appl. Phys. Lett. 86, 26, 262904 (2005)
  11. Z. Yao, H. Liu, M. Cao, H. Hao, Z. Yu. Mater. Res. Bull. 46, 8, 1257 (2011)
  12. Y. Dong, K. Zou, R. Liang, Z. Zhou. Prog. Mater. Sci. 132, 101026 (2023)
  13. J. Chen, H.M. Chan, M.P. Harmer. J. Am. Ceram. Soc. 72, 4, 593 (1989)
  14. G.A. Samara. J. Phys. Condens. Matter 15, 9, R367 (2003)
  15. W. Kleemann. Physica Status Solidi B 251, 10, 1993 (2014)
  16. S.K. Pandey, O.P. Thakur, D.K. Bhattacharya, C. Prakash, R. Chatterjee. J. Alloys. Compd, 468, 12, 356 (2009)
  17. C. Li, B. Xu, D. Lin, S. Zhang, L. Bellaiche, T.R. Shrout, F. Li. Phys. Rev. B 101, 14, 140102(R) (2020)
  18. H. Zhou, S. Yang, Z. Xi, S. Dong, F. Guo, W. Long, X. Li, P. Fang, Z. Dai. J. Mater. Sci. 56, 21, 12121 (2021)
  19. Z. Fang, X. Tian, F. Zheng, X. Jiang, W. Ye, Y. Qin, X. Wang, Y. Zhang. Ceram. Int. 48, 6, 7550 (2022)
  20. R.E. Eitel, T.R. Shrout, C.A. Randall. Jpn. J. Appl. Phys. 43, 12, 8146 (2004)
  21. Y. Chen, D. Lan, Q. Chen, Z. Xu, X. Yue, D. Xiao, J. Zhu. Mater. Res. Soc. Symp. Proc. 888, 1, _ (2006)
  22. Y. Chen, Y. Ma, D. Xue, J. Zhu. "Piezoelectric Ceramics" Int. Conf. on Materials Engineering and Information Technology Applications (MEITA), 853 (2015)
  23. F. Li, D. Lin, Z. Chen, Z. Cheng, J. Wang, C. Li, Z. Xu, Q. Huang, X. Liao, L.-Q. Chen, T.R. Shrout, S. Zhang. Nature Mater. 17, 4, 349 (2018)
  24. S.W. Cho, J.M. Baik, Y.H. Jeong. Ceram. Int. 49, 2, 1865 (2023)
  25. IEEE Standard on Piezoelectricity. ANSI/IEEE Std 176-1987. Institute of Electrical and Electronics Engineers Inc., New York (1987)
  26. M.-S. Lee, Y.H. Jeong. Ceram. Int. 49, 23, 37936 (2023)
  27. J.-H. Ji, D.-J. Shin, J. Kim, J.-H. Koh. Ceram. Int. 46, 4, 4104 (2020)
  28. X.X. Wang, X.G. Tang, K.W. Kwok, H.L.W. Chan, C.L. Choy. Appl. Phys. A 80, 5, 1071 (2005)
  29. P. Singh, S. Singh, J.K. Juneja, K.K. Raina, R.P. Pant, C. Prakash. Integrated Ferroelectrics 122, 1, 23 (2010)
  30. P.A. Pankrat'ev, E.P. Smirnova, V.N. Klimov, E.G. Guk, N.V. Zaitseva, A.V. Sotnikov, E.E. Mukhin. FTT 67, 3, 514 (2025). (in Russian)
  31. H. Ghayour, M. Abdellahi. Powder Technol. 292, 84 (2016). https://doi.org/10.1016/j.powtec.2016.01.030
  32. W.R. Buessem, L.E. Cross, A.K. Goswami. J. Am. Ceram. Soc. 49, 1, 34 (1966)
  33. G. Arlt, D. Hennings, G. de With. J. Appl. Phys. 58, 4, 1619 (1985)
  34. M.H. Frey, Z. Xu, P. Han, D.A. Payne. USA Ferroelectrics 206, 1, 337 (1998)
  35. W. Cao, C.A. Randall. J. Phys. Chem. Solids 57, 10, 1499 (1996)
  36. M. Demartin, D. Damjanovic. Appl. Phys. Lett. 68, 21, 3046 (1996)
  37. Z. Zhao, V. Buscaglia, M. Viviani, M.T. Buscaglia, L. Mitoseriu, A. Testino, M. Nygren, M. Johnsson, P. Nanni. Phys. Rev. B 70, 2, 024107 (2004).

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